Wave Oscillations in Colloid Oxyhydrates

Erscheinungsjahr 2010
ISBN: 978-0-87849-158-2
Verlag: Trans Tech Publications

Buch, Englisch, 512 Seiten, Format (B × H): 170 mm x 240 mm, Gewicht: 1100 g

Volume is indexed by Thomson Reuters BCI (WoS).The importance of coherent chemistry, that is, the chemistry of periodic oscillatory processes, is increasing at a rapid rate in specific chemical disciplines. While being perfectly understood and highly developed in the fields of physical chemistry, chemical physics and biological chemistry, the periodic developmental paradigm of processes and phenomena still remains poorly developed and misunderstood in classical inorganic chemistry and related branches, such as colloid chemistry. The probability is that we miss subtle colloid chemical phenomena that could be of utmost importance if taken into consideration when catalysis or adsorption is involved. The author here reveals all of the astonishing vistas that periodic wave paradigms open up to researchers in certain colloid chemical systems, and will doubtless stimulate researchers to look at them in a new light.

Autoren/Hrsg.

Sucharev, Yuri I.

Fachgebiete

• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde

Inhaltsverzeichnis

Preface
Table of Contents
Summary
1. Periodical Pulsation Ionic Flow Properties of Oxo-Olic Complexes of Zirconium and Silicium
1.1 Polymerization of the Hydrated Particles of Zirconium Oxyhydrate
1.2 Emission-Wave Duality of Behavior of the Periodical Processes in the D- and F-Elements’ Oxyhydrates. 1.3 Periodicity of the Efficient Diffusion Coefficients
1.4 Quantization of the Pacemakers’ Radiuses in Oxyhydrate Gels
1.5 Bifurcation of the Pacemakers’ Radius Doubling in Gel Oxyhydrate Systems
1.6 Extensional Dilatancy and Dimensions of the Pacemakers
1.7 The Periodical State Isotherm
Abstract 1.1
1.8 other Forms and Types of Oscillatory Motions in Oxyhydrate Systems
Abstract 1.2. Instrumental Support
2. Behavior of Zirconium Oxyhydrate Gels Affected by the Spontaneous Pulsating Electrical Currents
2.1 Theory
2.2 Synchronization of the Periodical Oxyhydrate Systems
2.3 Mathematical Modeling Problem
2.4 Connections between Certain Self-Organization Parameters
2.5 Conclusions
3. Zirconium Oxyhydrate Gels with Specifically Repeated Pulsation Macromolecules’ Organizations: the Experimental Aspect
3.1 Some of the TGM’s Experimental Results
3.2 Oxyhydrate Clusters Structuring in Non-Equilibrium Conditions
3.3 the Way the Ageing Time Affects the Sorption Properties of the Zirconium Oxyhydrate
3.4 Conclusions
4. Modeling of the Oxyhydrate Gels’ Shaping in an Active Excitable Medium. the Phase Transition Operator in Gels’ Oxyhydrates (the Liesegang Operator)
4.1 Modeling of Autowave Shaping Processes in D- and F- Elements’ Oxyhydrate Gels. the Simplest Mathematical Model of the Reaction-Diffusion Type
4.2 Studies of a Modeled Oxyhydrate System
4.3 Modeling of the Gel Shaping in an