Buch, Englisch, 586 Seiten, Previously published in hardcover, Format (B × H): 155 mm x 235 mm, Gewicht: 896 g
9-Borabicyclo [3.3.1] nonane (9-BBN)
Buch, Englisch, 586 Seiten, Previously published in hardcover, Format (B × H): 155 mm x 235 mm, Gewicht: 896 g
ISBN: 978-3-642-08034-0
Verlag: Springer
9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN’s derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations.
Zielgruppe
Research
Autoren/Hrsg.
Fachgebiete
- Medizin | Veterinärmedizin Medizin | Public Health | Pharmazie | Zahnmedizin Vorklinische Medizin: Grundlagenfächer Physik, Chemie, Biologie für Mediziner
- Medizin | Veterinärmedizin Medizin | Public Health | Pharmazie | Zahnmedizin Klinische und Innere Medizin Immunologie
- Naturwissenschaften Biowissenschaften Biochemie (nichtmedizinisch)
- Naturwissenschaften Chemie Organische Chemie
Weitere Infos & Material
General Remarks.- Preparation and Properties.- Kinetic Studies.- Hydroboration.- Synthesis of Alcohols.- Synthesis of Aldehydes and Ketones.- Synthesis of Carboxylic Acids.- Synthesis of Esters.- Synthesis of Nitriles.- Synthesis of (E)-?,?-Unsaturated Amides.- Synthesis of Amines.- Synthesis of Halides.- Synthesis of Dialkylsulfides.- Synthesis of Thiophene Oligomers.- Synthesis of Cyclopropanes and Cyclobutanes.- Synthesis of Borinanes.- Synthesis and Transformations of Butterflyboranes: cis-Bicyclo[3.3.0]oct-1-yldialkylboranes.- Synthesis of ?-Bromoboranes.- Synthesis of Borinates.- Synthesis and Transformation of Polymers.- Synthesis of Alkali Metal 9-Boratabicyclo[3.3.1] nonane (Li, K, and Na 9-BBNH).- Synthesis of B-R-9-BBN Not Available via Hydroboration.- Synthesis of Unsaturated Compounds.- Reduction.- Asymmetric Reduction.- Cleavage of Ethers.- trans-Metalation.- Separation of Isomers.- Diels-Alder Reaction.- Suzuki Reaction.- Miscellaneous Reactions.
