Organolithiums in Enantioselective Synthesis

Softcover Nachdruck of the original 1. Auflage 2003
ISBN: 978-3-662-14612-5
Verlag: Springer

Buch, Englisch, Band 5, 320 Seiten, Format (B × H): 155 mm x 235 mm, Gewicht: 511 g

Reihe: Topics in Organometallic Chemistry

This volume is the first dedicated to a comprehensive coverage of this rapidly developing transdisciplinary field. It provides a rich source of essential information on synthesizing molecules in an enantioselective manner using organolithiums, and serves as an inspiration for future developments.

Zielgruppe

Research

Autoren/Hrsg.

Hodgson, David M.

Fachgebiete

• Naturwissenschaften Chemie Anorganische Chemie
• Naturwissenschaften Chemie Organische Chemie Organometallchemie
• Naturwissenschaften Chemie Chemie Allgemein Pharmazeutische Chemie, Medizinische Chemie

Inhaltsverzeichnis

Overview of Organolithium-Ligand Combinations and Lithium Amides for Enantioselective Processes.- Enantioselective Addition of Organolithiums to C=O Groups and Ethers.- Enantioselective Conjugate Addition and 1,2-Addition to C=N of Organolithium Reagents.- Enantioselective Synthesis by Lithiation Adjacent to Oxygen and Electrophile Incorporation.- Enantioselective Synthesis by Lithiation Adjacent to Nitrogen and Electrophile Incorporation.- Enantioselective Synthesis by Lithiation Adjacent to Sulfur, Selenium or Phosphorus, or without an Adjacent Activating Heteroatom.- Enantioselective Synthesis by Lithiation Adjacent to Oxygen and Subsequent Rearrangement.- Enantioselective Synthesis by Lithiation to Generate Planar or Axial Chirality.- Enantioselective Carbolithiations.