Innovations in Ionic Liquid-Based Surfactants and Interfacial Phenomena

1. Auflage 2025
ISBN: 978-1-032-74807-8
Verlag: Taylor & Francis Ltd

Buch, Englisch, 376 Seiten, Format (B × H): 156 mm x 234 mm, Gewicht: 453 g

Reihe: Progress in Colloid and Interface Science

Innovations in Ionic Liquid-Based Surfactants and Interfacial Phenomena" offers a comprehensive exploration of ionic liquid-based surfactants (ILBSs) and their transformative potential. The book is divided into three sections. Section I establishes the fundamental properties of ionic liquids (ILs) and ILBSs, emphasizing their unique structures, environmental advantages, and flexible design. It details the diverse types of ILBSs, highlighting their individual characteristics and applications. Section II delves into the crucial interfacial behavior of ILBSs, examining their role in reducing interfacial tension, influencing micelle formation, enhancing emulsification processes, and modifying surface wettability. The mechanisms underlying these phenomena are thoroughly investigated, with particular attention paid to the impact of the structure of ILBSs on their performance. Section III showcases the broad applicability of ILBSs across various industries. Specific applications discussed include the stabilization of particle dispersions, the improvement of extraction techniques, and the significant enhancement of oil recovery from challenging reservoirs. The book bridges the gap between fundamental principles and practical applications, equipping the readers with the necessary knowledge to harness the revolutionary potential of ILBSs. It serves as an invaluable resource for researchers, academics, and professionals in this rapidly evolving field.

Zielgruppe

Academic, Postgraduate, Professional Practice & Development, and Professional Reference

Autoren/Hrsg.

Javadi, Aliyar

Kharazi, Mona

Saien, Javad

Miller, Reinhard

Fachgebiete

• Naturwissenschaften Chemie Chemie Allgemein
• Naturwissenschaften Physik Mechanik Energie
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Verfahrenstechnik, Chemieingenieurwesen

Inhaltsverzeichnis

Preface
Section I: Ionic Liquids Structure
Chapter 1: Characteristic Features
1.1. Introduction
1.2. General Features
1.2.1. Ionic liquids
1.2.2. Molten salts
1.3. Ionic Liquids Properties
1.3.1. Melting point
1.3.2. Vapor pressure
1.3.3. Thermal stability and non-flammability
1.3.4. Structural designability
1.3.5. Electrical conductivity
1.3.6. Viscosity
1.3.7. Liquid state over a wide temperature range
1.3.8. Magnetic property
1.3.9. Solvation potential
1.4. Summary
1.5. References
Chapter 2: Ionic Liquid-Based Surfactants
2.1. Introduction
2.2. Structure and Characteristics of Ionic Liquid-Based Surfactants
2.2.1. General consideration
2.2.2. Head group effects
2.2.3. Alkyl chain effects
2.2.4. Counter anion effects
2.2.5. Hydrophilic-lipophilic balance
2.3. Classification of Ionic Liquid-Based Surfactants
2.3.1. Single-chain ILBSs
2.3.2. Multicationic ILBSs
2.3.3. Zwitterionic ILBSs
2.3.4. Catanionic ILBSs
2.3.5. Novel ILBSs
2.4. Ionic Liquid-Based Surfactants and Green Chemistry
2.4.1. Toxicity
2.4.2. Biodegradability
2.5. Summary
2.6. References
Section II: Interfacial Phenomena
Chapter 3: Interface Properties AND Interfacial Tension Reduction
3.1. Introduction
3.2. Interfacial Tension Concepts
3.3. Methods of Determining Interfacial Tension
3.4. Role of Surfactant in Interfacial Tension Reduction
3.4.1. Dynamic interfacial tension
3.4.2. Adsorption models for surfactants at liquid interfaces
3.5. Ionic Liquid-Based Surfactants and Interfacial Tension Reduction
3.6. Impact of Ionic Liquid-Based Surfactants Structure on Interfacial Tension
3.6.1. Head group effects
3.6.2. Alkyl chain effects
3.6.3. Counter anion effects
3.6.4. Spacer effects
3.7. Comparing Effectiveness of Different Types of Ionic Liquid-Based Surfactants
3.7.1. Single-chain type ILBSs
3.7.2. Multicationic type ILBSs
3.7.3. Zwitterionic type ILBSs
3.7.4. Catanionic type ILBSs
3.8. Summary
3.9. References
Chapter 4: Micelle Formation
4.1. Introduction
4.2. Micelle and Critical Micelle Concentration Concepts
4.3. Micellar Structures
4.3.1. Structures and classification of micelles
4.3.2. Liquid crystals
4.3.3. Factors affecting micellar structures and packing parameter
4.3.4. Micellar aggregation number
4.4. Methods of Determining Critical Micelle Concentration
4.5. Ionic Liquid-Based Surfactants and Critical Micelle Concentration
4.6. Impact of Ionic Liquid-Based Surfactants Structure on Critical Micelle Concentration
4.6.1. Head group effects
4.6.2. Alkyl chain effects
4.6.3. Counter anion effects
4.6.4. Spacer effects
4.7. Comparing Effectiveness of Different Types of Ionic Liquid-Based Surfactants
4.7.1. Single-chain type ILBSs
4.7.2. Multicationic type ILBSs
4.7.3. Zwitterionic type ILBSs
4.7.4. Catanionic type ILBSs
4.8. Summary
4.9. References
Chapter 5: Emulsification
5.1. Introduction
5.2. Emulsification Concepts
5.3. Types of Emulsions
5.3.1. Classification based on the dispersed phase
5.3.2. Classification based on the size of the dispersed droplets
5.3.3. Classification based on the nature of emulsifier
5.3.4. Classification based on the Winsor types
5.4. Emulsion Stability
5.4.1. The DLVO theory and emulsion index
5.4.2. Destabilizing factors of emulsions
5.4.3. Stabilizing factors of emulsions
5.5. Ionic Liquid-Based Surfactants and Emulsification
5.6. Impact of Ionic Liquid-Based Surfactants Structure on Emulsification
5.6.1. Head group effects
5.6.2. Alkyl chain effects
5.6.3. Counter anion effects
5.7. Comparing Effectiveness of Different Types of Ionic Liquid-Based Surfactants
5.7.1. Single-chain type ILBSs
5.7.2. Multicationic type ILBSs
5.7.3. Zwitterionic type ILBSs
5.7.4. Catanionic type ILBSs
5.8. The Hydrophilic-Lipophilic Balance of Ionic Liquid-Based Surfactants
5.9. Summary
5.10. References
Chapter 6: Wettability Modifications
6.1. Introduction
6.2. Wetting and Wettability Concepts
6.2.1. Wetting and types
6.2.2. Wettability and its modification
6.3. Methods of Determining the Wettability
6.3.1. Surface and interfacial tension measurements
6.3.2. Contact angle measurements
6.3.3. Adsorption and spreading measurements
6.3.4. Wetting balance measurements
6.3.5. Imbibition measurements
6.4. Role of Surfactant in Wetting Modifications
6.4.1. Mechanism of surfactants adsorption at the solid surface
6.4.2. Wettability changes with surfactants
6.5. Ionic Liquid-Based Surfactants and Wettability Modification
6.6. Impact of Ionic Liquid-Based Surfactants Structure on Wettability Modification
6.6.1. Head group effects
6.6.2. Alkyl chain effects
6.6.3. Counter anion effects
6.7. Comparing Effectiveness of Different Types of Ionic Liquid-Based Surfactants
6.7.1. Single-chain type ILBSs
6.7.2. Multicationic type ILBSs
6.7.3. Zwitterionic type ILBSs
6.7.4. Catanionic type ILBSs
6.8. Summary
6.9. References
Section III: Applications
Chapter 7: Particle Dispersions
7.1. Introduction
7.2. Particle Dispersion Concepts
7.3. Mechanisms of Stabilizing Dispersions
7.3.1. Electrostatic stabilization
7.3.2. Steric stabilization
7.3.3. Electrosteric stabilization
7.4. Role of Surfactants in Dispersion of Particles
7.4.1. Wetting of powder
7.4.2. De-aggregating of particle clusters
7.4.3. Preventing re-aggregation of dispersed particles
7.5. Ionic Liquid-Based Surfactants and Particle Dispersion
7.6. Impact of Ionic Liquid-Based Surfactants Structure on Particle Dispersion
7.6.1. Head group effects
7.6.2. Alkyl chain effects
7.6.3. Counter anion effects
7.7. Comparing Effectiveness of Different Types of Ionic Liquid-Based Surfactants
7.7.1. Single-chain type ILBSs
7.7.2. Multicationic type ILBSs
7.7.3. Zwitterionic type ILBSs
7.7.4. Catanionic type ILBSs
7.8. Summary
7.9. References
Chapter 8: Extraction Processes
8.1. Introduction
8.2. Extraction Process Concepts
8.3. Mechanisms of Extraction Processes
8.3.1. Liquid-liquid extraction
8.3.2. Solid-liquid extraction
8.3.3. Solid-phase extraction and dispersive solid-phase extraction
8.4. Role of Surfactant in Extraction Processes
8.4.1. Impact on the liquid-liquid extraction
8.4.2. Impact on the solid-liquid extraction
8.4.3. Impact on the solid-phase extraction and dispersive solid-phase extraction
8.4.4. Impact on separation of extracted substance from the solvent
8.5. Ionic Liquid-Based Surfactants and Extraction Processes
8.6. Impact of Ionic Liquid-Based Surfactants Structure on Extraction Processes
8.6.1. Head group effects
8.6.2. Alkyl chain effects
8.6.3. Counter anion effects
8.7. Comparing Effectiveness of Different Types of Ionic Liquid-Based Surfactants
8.7.1. Single-chain type ILBSs
8.7.2. Multicationic type ILBSs
8.7.3. Zwitterionic type ILBSs
8.7.4. Catanionic type ILBSs
8.8. Summary
8.9. References
Chapter 9: Enhanced Oil Recovery
9.1. Introduction
9.2. Enhanced Oil Recovery Concepts
9.2.1. Primary crude oil recovery
9.2.2. Secondary crude oil recovery
9.2.3. Tertiary crude oil recovery
9.3. Role of Surfactant in Enhanced Oil Recovery
9.4. Ionic Liquid-Based Surfactants and Enhanced Oil Recovery
9.5. Enhanced Oil Recovery with Surfactant Flooding
9.5.1. Mechanism of surfactant flooding
9.5.2. Impact of ILBSs structure on surfactants flooding
9.5.3. Comparing effectiveness of different types of ILBSs
9.6. Enhanced Oil Recovery with Micellar Flooding
9.6.1. Mechanism of micellar flooding
9.6.2. Impact of ILBSs structure on micellar flooding
9.6.3. Comparing effectiveness of different types of ILBSs
9.7. Enhanced Oil Recovery with Wettability Alteration
9.7.1. Mechanism of wettability Alteration
9.7.2. Impact of ILBSs structure on wettability alteration
9.7.3. Comparing effectiveness of different types of ILBSs
9.8. Summary
9.9. References
Index I: Abbreviations
Index II: Name of ILBSs and Surfactants

Index III: Subject Index

Über Autor(innen)

Dr. Mona Kharazi

Dr. Mona Kharazi is an Assistant Professor at the Faculty of Chemistry and Petroleum Sciences at Bu-Ali Sina University, Hamedan, Iran, where she leads research on interfacial phenomena and their application to crude oil recovery. She received her B.Sc. (2012), M.Sc. (2015), and Ph.D. (2021) in applied chemistry from Bu-Ali Sina University. Following her Ph.D., she pursued postdoctoral research in chemical engineering, where she served as a project leader until 2023. Since 2024, Dr. Kharazi holds an Assistant Professor position in the Applied Chemistry Department at Bu-Ali Sina University. Her research interests span surface science, interfacial tension, ionic liquids, surfactants, nanomaterials, colloids, and green chemistry, with a particular emphasis on developing innovative experimental methods for enhanced oil recovery using novel materials. Dr. Kharazi co-authors over 60 journal articles, book chapters, and conference contributions, along with Iranian patents, focusing mainly on interdisciplinary research related to ionic liquid-based surfactants and crude oil recovery systems.

 

Websites: https://scholar.google.com/citations?user=jIkez6UAAAAJ&hl=en

https://www.researchgate.net/profile/Mona-Kharazi

E-mail: [e-mail]; [e-mail]

ORCID: 0000-0001-6645-0176

 Professor Javad Saien

Professor Javad Saien is a faculty member in the Faculty of Chemistry and Petroleum Sciences at Bu-Ali Sina University, Hamedan, Iran. He received his B.Sc. from Amir Kabir University of Technology (1984), his M.Sc. from the University of Tehran (1991), and his Ph.D. in Chemical Engineering from the University of Bradford, UK (1995). Since 1986, Professor Saien has been serving as an academic staff member at Bu-Ali Sina University, where he was promoted to full professor approximately 15 years ago. His research primarily focuses on enhanced oil recovery using ionic liquids and nanoparticles, wastewater treatment via homogeneous and heterogeneous processes, liquid-liquid extraction (including single drop, impinging streams, and LLE), and mass transfer intensification using external fields. Professor Saien has published over 200 journal articles, holds numerous national and international patents, and has authored several books and book chapters. Since 2020, he holds the position of Editor of the Journal of the Iranian Chemical Society and is a member of the editorial boards of various national and international scientific journals.

 

Website: https://profs.basu.ac.ir/saeen/

https://scholar.google.com/citations?user=V0yXsg8AAAAJ&hl=en

https://www.researchgate.net/profile/Javad-Saien

E-mails: [e-mail], [e-mail]

ORCID: 0000-0001-5731-022

Professor Aliyar Javadi

Aliyar Javadi is a pioneer scientist in dynamic surface phenomena, interfacial transport properties of multiphase processes and biointerfaces. He finished his B.Sc. (1996) in chemical engineering at Amirkabir University of Technology (Tehran Polytechnique), and M.Sc. (2000) and Ph.D. (2007) at Sharif University of Technology in Tehran, Iran. He continued research work at the Max Planck Institute for Colloids and Interfaces in Potsdam, Germany as postdoc and project leader.

Since 2013 Dr. Javadi has been appointed a professorship position at the Chemical Engineering Department of the University of Tehran, where he developed a working group and laboratory on “Dynamic surface phenomena and colloidal systems”. He is currently in collaboration with TU-Dresden and the Helmholtz Centre in Dresden-Rossendorf, Germany for developing new projects on dynamic surface phenomena and bio-interfaces, and scientific director of the World-Academies newly founded as knowledge management startup at the TU-Dresden for Remote Training and Research. His scientific achievements are published in more than 120 international journal papers and book chapters, mostly on dynamic interfacial properties of multiphase processes.

 

Websites: https://www.world-academies.com/members/javadi/;
https://tu-dresden.de/ing/maschinenwesen/ifvu/tpg/die-professur/beschaeftigte/Aliyar_Javadi; https://scholar.google.de/citations?user=DhbZvksAAAAJ&hl=de

E-Mail: [e-mail]; [e-mail]

ORCID: 0000-0002-9881-7304

Dr. habil. Reinhard Miller

Reinhard Miller is an associated senior scientist in the Institute for Condensed Matter Physics, Technical University of Darmstadt, Germany.

Reinhard Miller studied Mathematics at the University of Rostock and Colloid Science at the Technical University of Dresden, Germany. He made his PhD and habilitation at the Academy of Sciences in Berlin. In 1990, he was postdoc at the University of Toronto, Canada. From 1991 to 2019 he was group leader at the Max Planck Institute of Colloids and Interface in Potsdam. Since then, he continues his scientific work as associated senior scientist at the Technical University of Darmstadt.

His main scientific interests are dynamics and thermodynamics of adsorption of surfactants, proteins, polymers, particles and their mixtures at fluid interfaces, dilational and shear interfacial rheology, formation and stabilization of foams and emulsions. He published his scientific results in eight books, more than 650 papers in peer-reviewed journals, and many book chapters. He is editor of the journals Advances in Colloid and Interface Science and Editor-in-Chief for Colloids & Interfaces. He is also editor of the book series Progress in Colloid and Interface Science (CRC Press).

Website: https://www.ipkm.tu-darmstadt.de/research_ipkm/team_ipkm/team_ipkm_details_74624.de.jsp; https://scholar.google.de/citations?user=FEoPQ3UAAAAJ&hl=de

E-mail: [e-mail]

ORCID: 0000-0001-8943-7521