Contemporary Metal Boron Chemistry I

Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides
2008
ISBN: 978-3-540-78633-7
Verlag: Springer Berlin Heidelberg

Buch, Englisch, Band 130, 218 Seiten, HC runder Rücken kaschiert, Format (B × H): 160 mm x 241 mm, Gewicht: 518 g

Reihe: Structure and Bonding

TheC–halideandC–Hborylationchemistryhasbeendrivenby thedevelopment andbroadapplicationoftheSuzuki–Miyaura cross-coupling reaction[11],whichisnowoneofthemainC–Cbond-formingreactionsinthe arsenal of the organic chemist. Thus, the synthetic and structural chemistry ofmetalborylcomplexeshasgrownalongwithcatalyticapplicationsinwhich metal borylcomplexes are key intermediates. Likewise, the importance of metal borane?-complexes as intermediates in many catalytic reactions has only recently been recognized [12], and thisarea is now a rapidly expanding one.

Zielgruppe

Professional/practitioner

Autoren/Hrsg.

Lin, Zhenyang

Marder, Todd B.

Fachgebiete

• Naturwissenschaften Chemie Anorganische Chemie Nichtmetallische Chemie
• Naturwissenschaften Chemie Anorganische Chemie Festkörperchemie
• Naturwissenschaften Chemie Anorganische Chemie Komplexchemie

Inhaltsverzeichnis

Transition Metal Borylene Complexes.- Transition Metal Boryl Complexes.- Transition Metal ?-Borane Complexes.- Coordination Modes and Hydride Exchange Dynamics in Transition Metal Tetrahydroborate Complexes.