Phase Diagrams and Thermodynamic Modeling of Solutions

Erscheinungsjahr 2018
ISBN: 978-0-12-801494-3
Verlag: William Andrew Publishing

Buch, Englisch, 401 Seiten, Format (B × H): 191 mm x 235 mm, Gewicht: 1070 g

Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models.

Zielgruppe

<p>The book is primarily directed towards students and professionals doing research and development in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering and other fields of inorganic chemical and materials science and engineering.</p>

Fachgebiete

• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Technische Thermodynamik
• Naturwissenschaften Chemie Physikalische Chemie Thermochemie, Chemische Thermodynamik

Inhaltsverzeichnis

Part I Thermodynamics and Phase Diagrams1. Introduction2. Thermodynamic fundamentals3. Gibbs Phase Rule4. Fundamentals of the thermodynamics of solutions5. Binary T-composition phase diagrams6. Ternary T-composition phase diagrams7. General phase diagram sections8. Equilibrium and non-equilibrium cooling9. Aqueous and concentrated aqueous systems10. Phase diagrams involving second-order and higher-order transitions

Part II - Thermodynamic Modeling of Solutions11. Introduction12. Single-sublattice random-mixing (Bragg- Williams (BW)) models13. Single-sublattice models with short-range-ordering (SRO)14. Two-sublattice models - Molten salts15. Multiple sublattice models - The Compound Energy Formalism (CEF)16. The Modified Quasichemical Model in the quadruplet approximation17. Order-disorder transitions18. Applications of models to various classes of solutions

Exercises