Pinnavaia / Sayari / Jaroniec Nanoporous Materials II

1. Auflage 2000
ISBN: 978-0-08-053726-9
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, Band Volume 129, 916 Seiten, Web PDF

Reihe: Studies in Surface Science and Catalysis

The first symposium on Access in Nanoporous Materials was held in Lansing, Michigan on June 7-9, 1995. The five years that have passed since that initial meeting have brought remarkable advances in all aspects of this growing family of materials. In particular, impressive progress has been achieved in the area of novel self-assembled mesoporous materials, their synthesis, characterization and applications. The supramolecular self-assembly of various inorganic and organic species into ordered mesostructures became a powerful method for synthesis of mesoporous molecular sieves of tailored framework composition, pore structure, pore size and desired surface functionality for advanced applications in such areas as separation, adsorption, catalysis, environmental cleanup and nanotechnology.
In addition to mesostructured metal oxide molecular sieves prepared through supramolecular assembly pathways, clays, carbon molecular sieves, porous polymers, sol-gel and imprinted materials, as well as self-assembled organic and other zeolite-like materials, have captured the attention of materials researchers around the globe.
The contents of the current volume present a sampling of more than 150 oral and poster papers delivered at the Symposium on Access in Nanoporous Materials II held in Banff, Alberta on May 25-30, 2000. About 70% of the papers are devoted to the synthesis of siliceous mesoporous molecular sieves, their modification, characterization and applications, which represent the current research trend in nanoporous materials. The remaining contributions provide some indications on the future developments in the area of non-siliceous molecular sieves and related materials. This book reflects the current trends and advances in this area, which will certainly attract the attention of materials chemists in the 21st century.

Autoren/Hrsg.

Pinnavaia, T. J.

Sayari, Abdel

Jaroniec, M.

Inhaltsverzeichnis

1;Front Cover;1
2;Nanoporous Materials II;4
3;Copyright Page;5
4;Contents;6
5;Preface;16
6;Organizing Committee;17
7;International Advisory Committee;17
8;Part I: Synthesis of Mesoporous Silicas;18
8.1;Chapter 1. A Novel Approach to Polymer-template Mesoporous Molecular Sieves;18
8.2;Chapter 2. Synthesis of Uniform and Stable Millimeter-Sized Mesoporous Silica Ropes by the Addition of Polymer and Ammonia Hydrothermal Treatment;24
8.3;Chapter 3. The Synthesis and Characterization of Mesoporous Molecular Sieves MCM-41 with Interconnected Channels;32
8.4;Chapter 4. Synthesis of Mesoporous Silica Molecular Sieves via a Novel Templating Scheme;40
8.5;Chapter 5. Preparation of Spherical Micrometric MSU-X Mesoporous Silica Particles for Chromatography Applications;48
8.6;Chapter 6. Synthesis of Nanometer-sized Mesoporous Silica and Alumina Spheres;54
8.7;Chapter 7. Assembly of Nanoporous Silica via Amphoteric Surfactant Templating Scheme;62
8.8;Chapter 8. Formation of Integrated MCM-41 Mesostructure in Fluoride Medium: An Improvement of Hydrothermal Stability;66
8.9;Chapter 9. New Way to Synthesize MCM-41 and MCM-48 Materials with Tailored Pore Sizes;74
8.10;Chapter 10. Poly(oxyethylene) Oleyl Ethers as Templating Agents for the Synthesis of Large Pore Mesoporous Materials;84
8.11;Chapter 11. Pore Size Engineering of Mesoporous Silicas Using Alkanes as Swelling Agents;92
8.12;Chapter 12. Improvement of Hydrothermal Stability of Mesoporous Molecular Sieves of MCM- 41 Type;102
8.13;Chapter 13. Improvement on Thermal Stability and Acidity of Mesoporous Materials with Post- treatment of Phosphoric Acid;110
8.14;Chapter 14. In situ Synthesis of Micro- and Mesoporous Al-MFI / MCM-41 like Phases with High Hydrothermal Stability;116
8.15;Chapter 15. Microwave Synthesis of Micro-Mesoporous Composite Material;124
8.16;Chapter 16. Preparation of Y/ MCM-41 Composite Materials;134
8.17;Chapter 17. Supported Crystallization of MFI- and FER-type Molecular Sieves on Porous Glasses;138
8.18;Chapter 18. Supercritical Fluid Extraction of Amine Surfactant in Hexagonal Mesoporous Silica (HMS);148
8.19;Chapter 19. Performance of Tetraalkylammonium Ions during the Formation of Zeolites from Tetraethylorthosilicate;156
8.20;Chapter 20. Study of Interactions between Silicate Species and Surfactant Micelles in the Synthesis of Organized Mesoporous Materials;164
9;Part II: Synthesis of Framework-Modified Mesoporous Silicas;172
9.1;Chapter 21. Novel Ordered Mesoporous Materials with Hybrid Organic-Inorganic Network in the Frameworks;172
9.2;Chapter 22. Synthesis and Catalytic Application of Organically Modified Ti-MCM-41 Type Materials;180
9.3;Chapter 23. Influence of Silylation on the Catalytic Activity of Ti-MCM-41 during Epoxidation of Olefins;186
9.4;Chapter 24. Synthesis and Modification of Ti-containing Catalysts for Epoxidation of Alkene;196
9.5;Chapter 25. Synthesis and Adsorption Properties of Cerium Modified MCM-41;204
9.6;Chapter 26. Microwave Synthesis of Zr (Ti)-Si-Al HDN Catalytic Material;212
9.7;Chapter 27. Characterization of Mesoporous and Microporous Molecular Sieves Containing Niobium and Tantalum;218
9.8;Chapter 28. Direct Incorporation of Al in SBA Mesoporous Materials: Characterization, Stability and Catalytic Activity;226
9.9;Chapter 29. Post-Synthesis Alumination of MCM-41 by A1(NO3)3 (I): Improvement in Acidity for Purely Siliceous MCM-41;236
9.10;Chapter 30. Post-Synthesis Alumination of Si-MCM-41 by A1(NO3)3 (H): Enhancement of Hydrothermal, Mechanical and Chemical Stabilities;244
9.11;Chapter 31. Siting of Co(II), Zn(II) and Cu(I) Ions in (A1)MCM-41;252
9.12;Chapter 32. Reversible Transition of the Coordination of Al in MCM-41;260
10;Part III: Synthesis of Surface-Modified Mesoporous Silicas;268
10.1;Chapter 33. Functionalised Mesoporous Materials for Green Chemistry;268
10.2;Chapter 34. Peculiarities of Alkyl-modification of Ordered Mesoporous Materials: A Single- step Treatment on Uncalcined MCM-41 Involving Template Removal and Surface Functionalization;282
10.3;Chapter 35. New Organically Modified Hexagonal Mesoporous Silicas: Preparation and Applications in Catalysis;292
10.4;Chapter 36. Organo-functionalized Surface Modified MCM-41 Type Mesoporous Materials Having Various Organic Functional Groups;300
10.5;Chapter 37. Phenyl-functionalized Silicate Mesophases with Hexagonal or Cubic Symmetries: Influence of Synthesis Parameters;304
10.6;Chapter 38. Covalent Attachment of Dye Molecules to the Inner Surface of MCM-41;312
10.7;Chapter 39. Preparation and Characterization of Metal-Chalcogenide/MCM-41 Complexes;320
10.8;Chapter 40. Studies on Immobilization of Co(II)-La(III) Schiff Base Complex in MCM-41;328
10.9;Chapter 41. The Use of Alkylchlorosilanes as Coupling Agents for the Synthesis of Stable, Hydrophobic, Surfactant Extracted MCM-48/VOx Catalysts;334
10.10;Chapter 42. Epoxidation over Niobium and Titanium Grafted MCM-41 and MCM-48 Mesoporous Molecular Sieves;344
10.11;Chapter 43. Titanium Iso-propoxide Grafting on M41S Type Hosts: Catalytic and Adsorption Study;352
10.12;Chapter 44. Ternary Transition Metal Oxides within Mesoporous MCM-48 Silica Phases: Synthesis and Characterization;358
10.13;Chapter 45. The Inclusion of Polymeric Carbon in Channels of the Siliceous MCM-41 Mesoporous Molecular Sieve;366
11;Part IV: Synthesis of Other Nanoporous and Nanostructured Materials;374
11.1;Chapter 46. On the Way to New Nanoporous Transition Metal Oxides;374
11.2;Chapter 47. First Synthesis of Mesostructured Hexagonal Germanium Sulfides Using Gemini Surfactants;384
11.3;Chapter 48. Synthesis and Characterization of Mesostructured Molybdenum Sulfides with Intercalated Cationic Surfactants;392
11.4;Chapter 49. Synthesis and Characterization of Novel Mesostructured Tungsten Sulfides;400
11.5;Chapter 50. The Mesopores Developed during Boronation of Zeolites beta;408
11.6;Chapter 51. Mesostructured Clay Catalysts: a New Porous Clay Heterostructure (PCH) derived from synthetic saponite;418
11.7;Chapter 52. Al-Modified Porous Clay Heterostructures with Combined Micro- and Mesoporosity;426
11.8;Chapter 53. Mesoporous Synthetic Clays: Synthesis, Characterizationand Use as HDS Catalyst Supports;434
11.9;Chapter 54. Techniques for Tailoring the Pore Structure of SiO2-TiO2 Sol Pillared Clays;442
11.10;Chapter 55. Porous Smectite-type Materials Containing Catalytically Active Divalent Cations in Octahedral Sheets;452
11.11;Chapter 56. LDH-Surfactant Composite Nanoribbons;460
11.12;Chapter 57. Synthesis and Characterization of a New Sn-incorporated CoAl-layered Double Hydroxide (LDH) and Catalytic Performance of Co-spinel Microcrystallites in the Partial Oxidation of Methanol;468
11.13;Chapter 58. Construction Strategies for New Generation Micro-porous Solids;476
11.14;Chapter 59. Preparation Effects on Titania-sulfate Aerogel Morphology;484
11.15;Chapter 60. Distribution of Pt Clusters in SiO2 and TiO2 Nanotubes;492
11.16;Chapter 61. Catalytic Formation of Carbon Nanotubes on Fe-loading Molecular Sieves Materials: An XPS Study;500
12;Part V: Characterization of Nanoporous Materials;508
12.1;Chapter 62. Probing the Pore Space in Mesoporous Solids with NMR Spectroscopy and Magnetic Resonance Microimaging;508
12.2;Chapter 63. Characterization of Mesoporous Molecular Sieves: Differences between M41S and Pillared Layered Zeolites;518
12.3;Chapter 64. Magnetic Resonance Microimaging Studies of Porous Petroleum Coke;526
12.4;Chapter 65. Effect of Pore Size on the Adsorption of Xenon on Mesoporous MCM-41 and on the 129Xe NMR Chemical Shifts: a Variable Temperature Study;534
12.5;Chapter 66. What Does TEM Tell Us about Mesoporous Silica;542
12.6;Chapter 67. Transmission Electron Microscopy–an Indispensable Tool for the Characterisation of M41S-type Materials;552
12.7;Chapter 68. SEM and TEM Investigations of Macroporous and Toroidal Mesostructured Transition Metal Oxides;560
12.8;Chapter 69. 1H, 2H and 29Si Solid State NMR Study of Guest Acetone Molecules Occupying the Zeolitic Channels of Partially Dehydrated Sepiolite Clay;568
12.9;Chapter 70. In-situ Small Angle X-ray Scattering (SAXS) Studies on the Formation of Mesostructured Aluminophosphate / Surfactant Composite Materials;576
12.10;Chapter 71. Thermogravimetric Characterization of Mesoporous Molecular Sieves;584
12.11;Chapter 72. Self-consistent Determination of the Lamellar Phase Content in MCM-41 Using X- ray Diffraction, Nitrogen Adsorption and Thermogravimetry;594
12.12;Chapter 73. Recent Advances in Adsorption Characterization of Mesoporous Molecular Sieves;604
12.13;Chapter 74. Calculations of Pore Size Distributions in Nanoporous Materials from Adsorption and Desorption Isotherms;614
12.14;Chapter 75. Determination of Pore Size Distribution of Mesoporous Materials by Regularization;624
12.15;Chapter 76. The Sorption of n-Butyl and tert-Butyl Alcohols by Phenyl-Modified Porous Silica;634
12.16;Chapter 77. Change of Reorientational-vibrational Relaxation upon Capillary Condensation in Silica Mesopores;640
12.17;Chapter 78. Characterisation of Microporous Materials by Dynamic Sorption Methods;650
12.18;Chapter 79. Diffusion of High Molecular Weight Hydrocarbons in MesoStructured Materials of the MCM-41 Type;656
12.19;Chapter 80. Modeling Single-Component Permeation Through A Zeolite Membrane from Atomic-scale Principles;666
12.20;Chapter 81. Adsorption and Transport of Polyatomic Species in One-dimensional Systems: Exact Forms of the Thermodynamic Functions and Chemical Diffusion Coefficient;672
12.21;Chapter 82. Mechanical Strength of Micelle-Templated Silicas (MTS);682
12.22;Chapter 83. Structural Analysis of Hexagonal Mesoporous Silica Films Produced from Triblock-Copolymer-Structuring Sol-Gel;690
12.23;Chapter 84. On Structure/Property Relations in Nanoporous Semiconductors of the Cetineite- type;700
12.24;Chapter 85. Structural and Textural Properties of Zinc (Il)-Chromium (III) Spinel Oxides Prepared Using a Hydrotalcite-like Compound;708
12.25;Chapter 86. New Porous Composite Material–Characterization and Properties;718
12.26;Chapter 87. Stabilized Cluster Formation of Supercritical Xe in Carbon Nanopores;728
13;Part VI: Applications of Nanoporous and Nanostructured Materials;738
13.1;Chapter 88. Adsorption of Halocarbons in Nanoporous Materials: Current Status and Future Challenges;738
13.2;Chapter 89. Synthesis and Applications of Functionalized Nanoporous Materials for Specific Adsorption;746
13.3;Chapter 90. Non-electrostatic Surfactant Assembly Routes to Functionalized Nanostructured Silica: Prospects for Environmental Applications;756
13.4;Chapter 91. The Use of Mesoporous Silica in Liquid Chromatography;764
13.5;Chapter 92. Pressure Swing Adsorption of Butanone on Silica MCM-41;774
13.6;Chapter 93. Mercury-Sorption Characteristics of Nanoscale Metal Sulfides;782
13.7;Chapter 94. New Chiral Hybrid Organic-Inorganic Mesoporous Materials for Enantioselective Epoxidation;790
13.8;Chapter 95. The Direct Enantioselective Synthesis of Diols from Olefins using Hybrid Catalysts of Chiral Salen Cobalt Complexes Immobilized on MCM-41 and Titanium-containing Mesoporous Zeolite;798
13.9;Chapter 96. Nano-Clusters, Enantioselective Catalysis and Molecular Recognition Contrast Agents in MCM-41 - Part I;806
13.10;Chapter 97. Nano-Clusters, Enantioselective Catalysis and Molecular Recognition Contrast Agents in MCM-41 - Part II;814
13.11;Chapter 98. Photoactive Characteristics of Rhenium Complex Encapsulated in AIMCM-41 by Ion-exchange Method;824
13.12;Chapter 99. Physico-chemical and Catalytic Properties of MCM-41 Mesoporous Molecular Sieves Containing Transition Metals (Cu, Niand Nb);830
13.13;Chapter 100. Activity Enhancement of Mesoporous Silicate FSM-16 by Metal Ion-exchange and Sulfiding with Hydrogen Sulfide for Acid-catalyzed Reactions;840
13.14;Chapter 101. Application of Disordered Mesoporous Molecular Sieve KIT-1 as a Support for Energy/environmental Catalysts;848
13.15;Chapter 102. Radical Type Catalytic Sites on Mesoporous Silica;854
13.16;Chapter 103. Tungstate and Molybdate Exchanged Layered Double Hydroxides (LDHs) as Catalysts for Selective Oxidation of Organics and for Bleaching;862
13.17;Chapter 104. Mediating Effect of CO2 in Base-Catalysis by Zeolites;868
13.18;Chapter 105. Effective Sol-gel Adsorbents of Water Vapor Prepared Using Ethyl Silicate 40 as a Silica Precursor;876
13.19;Chapter 106. Photochromism of an Azobenzene in a Nanoporous Silica Film;882
13.20;Chapter 107. Silica-CTAB-Water Phase Diagram at 150°C: Predicting Phase Structure by Artificial Neural Network;888
14;Author Index;896
15;Subject Index;902
16;Studies in Surface Science and Catalysis;908