Schmidt Catalysis of Organic Reactions

Twenty-first Conference
Erscheinungsjahr 2006
ISBN: 978-1-4200-0779-4
Verlag: Taylor & Francis
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 552 Seiten

Reihe: Chemical Industries

Bringing together academic, industrial, and governmental researchers and developers, Catalysis of Organic Reactions comprises 57 peer-reviewed papers on the latest scientific developments in applied catalysis for organic reactions. The volume describes the use of both heterogeneous and homogeneous catalyst systems and includes original research articles on processes with potential industrial applications. The contributors, renowned leaders in the field, discuss noteworthy findings that include the award-winning studies by Isamu Yamauchi on metastable precursors to Raney® catalysts and by Gadi Rothenberg on methods for finding the best homogeneous catalysts. The book covers the synthesis of fine chemicals and pharmaceutical intermediates, solid acid catalysis, selective oxidation, chiral synthesis, combinatorial methods, nanotechnology, and “green” processes. These topics are organized by broad groupings based on major process types, such as hydrogenations and oxidations, or themes, such as novel methods and environmental consciousness. Covering the most recent significant developments in catalysis, this compilation is ideal for chemists and chemical engineers who apply homogeneous and heterogeneous catalysis in the synthesis of pharmaceutical, fine, or commodity chemicals.

Zielgruppe

Organic, industrial, and applied chemists and chemical engineers.

Autoren/Hrsg.

Schmidt, Stephen R.

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie

Inhaltsverzeichnis

Board of Editors
Chronology of Organic Reactions Catalysis Society Conferences
Preface
Symposium on Catalysis in Organic Synthesis
On the Use of Immobilized Metal Complex Catalysts in Organic Synthesis
Christopher W. Jones, Michael Holbach, John Richardson, William Sommer, Marcus Weck, Kunquan Yu, and Xiaolai Zheng
Supported Re Catalysts for Metathesis of Functionalized Olefins
Anthony W. Moses, Heather D. Leifeste, Naseem A. Ramsahye, Juergen Eckert, and Susannah L. Scott
Catalytic Hydrogenation of a Schiff’s Base over Pd/Carbon Catalysts: Kinetic Prediction of Impurity Fate and Byproduct Formation
Steve S.Y. Wang, William F. Merkl, Hyei-Jha Chung, Wendel Doubleday, and San Kiang
Halophosphite Ligands for the Rhodium Catalyzed Low-Pressure Hydroformylation Reaction
Thomas A. Puckette
Development of a Monolithic Bioreactor: Tailor-Made Functionalized Carriers
Karen M. de Lathouder, Freek Kapteijn, and Jacob A. Moulijn
Highly Selective Preparation of trans-4-Aminocyclohexane Carboxylic Acid from cis-Isomer over Raney® Nickel Catalyst
Sándor Gobölös, Zoltán Banka, Zoltán Tóth, János Szammer, and József L. Margitfalvi
Gas-Phase Acetone Condensation over Hydrotalcite-like Catalysts
Francisco Tzompantzi, Jaime S. Valente, Manuel S. Cantú, and Ricardo Gómez
Gas Phase Trimerization of Isobutene Using Green Catalysts  Angeles Mantilla, Francisco Tzompantzi, Miguel Torres, and Ricardo Gómez
Synthesis of Methyl Isobutyl Ketone over a Multifunctional Heterogeneous Catalyst: Effect of Metal and Base Components on Selectivity and Activity
Arran S. Canning, Jonathan J. Gamman, S. David Jackson, and Strath Urquart
The Control of Regio- and Chemo-Selectivity in the Gas-Phase, Acid-Catalyzed Methylation of 1,2-Diphenol (Catechol)
Mattia Ardizzi, Nicola Ballarini, Fabrizio Cavani, Luca Dal Pozzo, Luca Maselli, Tiziana Monti, and Sara Rovinetti
The Environmentally Benign, Liquid-Phase Benzoylation of Phenol Catalyzed by H-ß Zeolite. An Analysis of the Reaction Scheme
Mattia Ardizzi, Nicola Ballarini, Fabrizio Cavani, Massimo Cimini, Luca Dal Pozzo, Patrizia Mangifesta, and Diana Scagliarini
Symposium on Catalytic Oxidation
Biphasic Catalytic Oxidation of Hydrocarbons Using Immobilized Homogeneous Catalyst in a Microchannel Reactor
Jianli Hu, Guanguang Xia, James F. White, Thomas H. Peterson, and Yong Wang

Reaction Pathways for Propylene Partial Oxidation on Au/TiO2
Rahul Singh and Steven S.C. Chuang
The Transformation of Light Alkanes to Chemicals: Mechanistic Aspects of the Gas-Phase Oxidation of n-Pentane to Maleic Anhydride and Phthalic Anhydride
Mirko Bacchini, Nicola Ballarini, Fabrizio Cavani, Carlotta Cortelli, Stefano Cortesi, Carlo Fumagalli, Gianluca Mazzoni, Tiziana Monti, Francesca Pierelli, and Ferruccio Trifirò
Transition Metal Free Catalytic Aerobic Oxidation of Alcohols under Mild Conditions Using Stable Nitroxyl Free Radicals
Setrak K. Tanielyan, Robert L. Augustine, Clementina Reyes, Nagendranath Mahata, Michael Korell, and Oliver Meyer
The Conversion of Aminoalcohols to Aminocarboxylic Acid Salts over Chromia-Promoted Skeletal Copper Catalysts
Dongsheng S. Liu, Noel W. Cant, and Andrew J. Smith
Bromine-Free TEMPO-Based Catalyst System for the Oxidation of Primary and Secondary Alcohols Using NaOCl as the Oxidant
Setrak K. Tanielyan, Robert L. Augustine, Indra Prakash, Kenneth E. Furlong, and Handley E. Jackson
In situ Infrared Study of Catalytic Oxidation over Au/TiO2 Catalysis
Duane D. Miller and Steven S.C. Chuang
Symposium on Catalytic Hydrogenation
2006 Murray Raney Award Lecture: Synthesis and Features of New Raney® Catalysts from Metastable Precursors
Isamu Yamauchi
Competitive Hydrogenation of Nitrobenzene, Nitrosobenzene and Azobenzene
Elaine A. Gelder, S. David Jackson, and C. Martin Lok
Selective Hydrogenation of Dehydrolinalool to Linalool Using Nanostructured Pd-Polymeric Composite Catalysts
Linda Z. Nikoshvili, Ester M. Sulman, Galine N. Demidenko, Valentina G. Matveeva, Mikhail G. Sulman, Ludmila M. Bronstein, Petr M. Valetskiy, and Irina B. Tsvetkova
Modeling and Optimization of Complex Three-Phase Hydrogenations under Mass-Transfer Limitation and Catalyst Deactivation
Tapio O.Salmi, Dmitry Yu.Murzin, Johan P.Wärnå, Jyri-Pekka Mikkola, Jeanette E.B. Aumo, and Jyrki I. Kuusisto
The Effects of Various Catalyst Modifiers on the Hydrogenation of Fructose to Sorbitol and Mannitol
Daniel J. Ostgard, Virginie Duprez, Monika Berweiler, Stefan Röder, and Thomas Tacke
Cavitating Ultrasound Hydrogenation of Water-Soluble Olefins Employing Inert Dopants: Studies of Activity, Selectivity and Reaction Mechanisms
Robert S. Disselkamp, Sarah M. Chajkowski, Kelly R. Boyles, Todd R. Hart, and Charles H.F. Peden
The Treatment of Activated Nickel Catalysts for the Selective Hydrogenation of Pynitrile
Daniel J. Ostgard, Felix Roessler, Reinhard Karge, and Thomas Tacke
Deactivation of Sponge Nickel and Ru/C Catalysts in Lactose and Xylose Hydrogenations
Jyrki Kuusisto, Jyri-Pekka Mikkola, and Tapio Salmi
Selectivity Control in 1-Phenyl-1-Propyne Hydrogenation: Effect of Modifiers
S. David Jackson and Ron R. Spence
Hydrogenation and Isomerization Reactions of Olefinic Alcohols Catalyzed in Homogeneous Phase by Rh(I) Complexes
Maria G. Musolino, Giuseppe Apa, Andrea Donato, and Rosario Pietropaolo
Reductive Amination of Isobutanol to Diisobutylamine on Vanadium Modified Raney® Nickel Catalyst
Sándor Gobölös and József L. Margitfalvi
Symposium on Novel Methods in Catalysis of Organic Reactions
How to Find the Best Homogeneous Catalyst
Gadi Rothenberg, Jos A. Hageman, Frédéric Clerc, Hans-Werner Frühauf, and Johan A. Westerhuis
Novel Chloroaluminate Ionic Liquids for Arene Carbonylation
Ernesto J. Angueira and Mark G. White
Chemoselective Hydrogenation of Nitro Compounds to the Corresponding Amines on Raney® Copper Catalysts
Simon Robitaille, Genevieve Clément, Jean Marc Chapuzet, and Jean Lessard
Selective Hydrogenolysis of Sugar Alcohols over Structured Catalysts
Chunshe (James) Cao, James F. White, Yong Wang, and John G. Frye
Twinphos: A New Family of Chiral Ferrocene Tetra-Phosphine Ligands for Asymmetric Catalytic Transformations
Benoit Pugin, Heidi Landert, Martin Kesselgruber, Hans Meier, Richard Sachleben, Felix Spindler, and Marc Thommen
Catalyst Library Design for Fine Chemistry Applications
József L. Margitfalvi, András Tompos, Sándor Gobölös, Emila Tálas, and Mihály Hegedus
Dendrimer Templates for Pt and Au Catalysts
Bethany J. Auten, Christina J. Crump, Anil R. Singh, and Bert D. Chandler
Symposium on Acid and Base Catalysis
Development of an Industrial Process for the Lewis Acid/Iodide Salt-Catalyzed Rearrangement of 3,4-Epoxy-1-Butene to 2,5-Dihydrofuran
Stephen N. Falling, John R. Monnier, Gerald W. Phillips, Jeffrey S. Kanel, and Stephen A. Godleski
A New Economical and Environmentally Friendly Synthesis of 2,5-Dimethyl-2,4-Hexadiene
Alessandra O. Bianchi, Valerio Borzatta, Elisa Poluzzi, and Angelo Vaccari
Supported Heteropoly Acid Catalysts for Friedel-Crafts Acylation Kenneth G. Griffin, Peter Johnston, Roger Prétôt, and Paul A. van der Schaaf
Synthesis of Pseudoionones by Aldol Condensation of Citral with Acetone on Li-Modified MgO Catalyst
Veronica K. Diez, Juana I. Di Cosimo, and Carlos Apesteguía
The One Step Synthesis of MIBK via Catalytic Distillation: A Preliminary Pilot Scale Study
William K. O’Keefe, Ming Jiang, Flora T.T. Ng, and Garry L. Rempel
Symposium on “Green” Catalysis
Producing Polyurethane Foam from Natural Oil 
Aaron Sanders, David Babb, Robbyn Prange, Mark Sonnenschein, Van Delk, Chris Derstine, and Kurt Olson
Carbonylation of Chloropinacolone: A Greener Path to Commercially Useful Methyl Pivaloylacetate
Joseph R. Zoeller and Theresa Barnette
Recycling Homogeneous Catalysts for Sustainable Technology Jason P. Hallett, Pamela Pollet, Charles A. Eckert, and Charles L. Liotta
“Green” Catalysts for Enhanced Biodiesel Technology
Anton A. Kiss, Gadi Rothenberg, and Alexandre C. Dimian
Continuous Deoxygenation of Ethyl Stearate: A Model Reaction for Production of Diesel Fuel Hydrocarbons
Mathias Snåre, Iva Kubicková, Päivi Mäki-Arvela, Kari Eränen, and Dmitry Yu. Murzin

Glycerol Hydrogenolysis to Propylene Glycol under Heterogeneous Conditions
Simona Marincean, Lars Peereboom, Yaoyan Xi, Dennis J. Miller, and James E. Jackson
Developing Sustainable Process Technology
Joseph A. Kocal
Selective Oxidation of Propylene to Propylene Oxide in CO2 Expanded Liquid System
Hyun-Jin Lee, Tie-Pan Shi, Bala Subramaniam, and Daryle H. Busch
Symposium on Other Topics in Catalysis
catASium® M: A New Family of Chiral Bisphospholanes and their Application in Enantioselective Hydrogenations
Thomas H. Riermeier, Axel Monsees, Jens Holz, Armin Börner, and John Tarabocchia
Synthesis of Chiral 2-Amino-1-Phenylethanol
Robert Augustine, Setrak Tanielyan, Norman Marin, and Gabriela Alvez
Selective Tertiary-Butanol Dehydration to Isobutylene via Reactive Distillation and Solid Acid Catalysis
John F. Knifton and John R. Sanderson
Leaching Resistance of Precious Metal Powder Catalysts—Part 2
Tim Pohlmann, Kimberly Humphries, Jaime Morrow, Tracy Dunn, Marisa Cruz, Konrad Möbus, and Baoshu Chen
Optimization of Reductive Alkylation Catalysts by Experimental Design
Venu Arunajatesan, Marisa Cruz, Konrad Möbus, and Baoshu Chen
Accelerated Identification of the Preferred Precious Metal Powder Catalysts for Selective Hydrogenation of Multi-Functional Substrates
Dorit Wolf, Steffen Seebald, and Thomas Tacke
Transition Metal Removal from Organic Media by Deloxan® Metal Scavengers
Jaime B. Woods, Robin Spears, Jürgen Krauter, Tim McCarthy, Micheal Murphy, Lee Hord, Peter Doorley, and Baoshu Chen
Electroreductive Pd-Catalyzed Ullmann Reactions in Ionic Liquids
Laura Durán Pachón and Gadi Rothenberg
Author Index
Keyword Index