Su / Sanchez / Yang Hierarchically Structured Porous Materials

From Nanoscience to Catalysis, Separation, Optics, Energy, and Life Science
1. Auflage 2011
ISBN: 978-3-527-63960-1
Verlag: Wiley-VCH
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 652 Seiten, E-Book

This first book devoted to this hot field of science covers materials with bimodal, trimodal and multimodal pore size, with an emphasis on the successful design, synthesis and characterization of all kinds of hierarchically porous materials using different synthesis strategies. It details formation mechanisms related to different synthesis strategies while also introducing natural phenomena of hierarchy and perspectives of hierarchical science in polymers, physics, engineering, biology and life science. Examples are given to illustrate how to design an optimal hierarchically porous material for specific applications ranging from catalysis and separation to biomedicine, photonics, and energy conversion and storage. With individual chapters written by leading experts, this is the authoritative treatment, serving as an essential reference for researchers and beginners alike.

Autoren/Hrsg.

Su, Bao-Lian

Sanchez, Clément

Yang, Xiao-Yu

Inhaltsverzeichnis

Preface   PART I: Introduction   INSIGHTS INTO HIERARCHICALLY STRUCTURED POROUS MATERIALS: FROM NANOSCIENCE TO CATALYSIS, SEPARATION, OPTICS, ENERGY, AND LIFE SCIENCE Introduction Synthesis Strategies to Hierarchically Structured Porous Materials Emerging Applications of Hierarchically Structural Porous Materials Conclusions   HIERARCHY IN NATURAL MATERIALS Natural Materials as a Source of Inspiration in Materials Science Hierarchies Based on Fiber Architectures Liquid Crystalline Assemblies, Clues to Mimic Hierarchical Structures Mineralized Biological Tissues, Models for Hybrid Materials Concluding Remarks   PART II: Synthesis Strategies to Hierarchically Structured Porous Materials   Hierarchically Structured Porous Materials by Dually Micellar Templating Approach Introduction Nanocasting - True Liquid Crystalline Templating 3.3 Basics of Micellization Mixed Surfactant Solutions Hierarchical Self-Assembly of Concentrated Aqueous Surfactant Mixtures - Hierarchical Mesoporous Structures Conclusions   COLLOIDAL CRYSTAL TEMPLATING APPROACHES TO MATERIALS WITH HIERARCHICAL POROSITY Introduction and Historical Overview The Preparation of 3DOM Materials 3DOM Materials with Intrinsic Secondary Porosity Hierarchical Materials from Multimodal Colloidal Crystal Templates Hierarchical Materials from Combinations of Soft and Colloidal Crystal Templating Hierarchical Opals and Related Structures Conclusions and Outlook   TEMPLATING OF MACROPOROUS OR SWOLLEN MACROSTRUCTURED POLYMERS Introduction Macroporous Polymer Gels Formed in Amphiphile Solutions Macroporous Starch or Agarose Gels Polymer Foams Polymeric Films and Fibrous Mats Polymer Spheres Closing Remarks   BIOINSPIRED APPROACH TO SYNTHESIZING HIERARCHICAL POROUS MATERIALS Introduction Hierarchical Porous Materials from Biotemplates Hierarchical Porous Materials from the Biomimetic Process Conclusions and Perspectives   POROUS MATERIALS BY TEMPLATING OF SMALL LIQUID DROPS Introduction Emulsion Templating Breath Figures Templating Conclusions   HIERARCHICALLY POROUS MATERIALS BY PHASE SEPARATION: MONOLITHS Introduction Background and Concepts Examples of Materials with Controlled Macro/Mesopores Summary   FEATURE SYNTHESIS OF HIERARCHICALLY POROUS MATERIALS BASED ON GREEN EASY-LEACHING CONCEPT Introduction Hierarchically Structured Porous Materials Synthesized by Easy-Leaching Air Templates Hierarchically Structured Porous Materials Synthesized by Easy-Leaching Ice Template Hierarchically Structured Porous Materials Synthesized by Easy Selective-Leaching Method Other Easy-Leaching Concepts in the Synthesis of Hierarchically Structured Porous Materials Summary   INTEGRATIVE CHEMISTRY ROUTES TOWARD ADVANCED FUNCTIONAL HIERARCHICAL FOAMS Introduction Organic-Inorganic PolyHIPEs Prepared from Water-in-Oil Emulsions Organic-Inorganic PolyHIPEs Prepared from Direct Emulsions Particles-Stabilized PolyHIPE Conclusion and Perspectives   HIERARCHICALLY STRUCTURED POROUS COATINGS AND MEMBRANES Introduction The Multiple Templating Strategy Dynamic Templating Building Block Assemblies for Photonic Band Gap Materials Ink-Jet Printing and Cooperative Self-Assembly Foaming Processes Filtration Membranes Conclusion   SELF-FORMATION PHENOMENON TO HIERARCHICALLY STRUCTURED POROUS MATERIALS Introduction History of Self-Formation Phenomenon Features of Self-Formation Phenomenon Structural Features of Hierarchical Porous Materials Based on the Self-Formation Phenomenon The Mechanism of Self-Formation Procedure Controlled Synthesis Based on the Self-Formation Phenomena Development of Synthesis Methodology Applications and Hierarchical Catalysis Summary   AUTO-GENERATED HIERARCHICAL MESO-MACROPOROUS ALUMINOSILICATE MATERIALS WITH HIGH TETRAHEDRAL AL CONTENT FROM THE SINGLE-MOLECULAR ALKOXY-PRECURSOR (SMAP) STRATEGY Introduction Hierarchically Structured Meso-Macroporous Aluminosilicates Conclusion   ZEOLITES WITH HIERARCHICALLY POROUS STRU

Preface   PART I: Introduction   INSIGHTS INTO HIERARCHICALLY STRUCTURED POROUS MATERIALS: FROM NANOSCIENCE TO CATALYSIS, SEPARATION, OPTICS, ENERGY, AND LIFE SCIENCE Introduction Synthesis Strategies to Hierarchically Structured Porous Materials Emerging Applications of Hierarchically Structural Porous Materials Conclusions   HIERARCHY IN NATURAL MATERIALS Natural Materials as a Source of Inspiration in Materials Science Hierarchies Based on Fiber Architectures Liquid Crystalline Assemblies, Clues to Mimic Hierarchical Structures Mineralized Biological Tissues, Models for Hybrid Materials Concluding Remarks   PART II: Synthesis Strategies to Hierarchically Structured Porous Materials   Hierarchically Structured Porous Materials by Dually Micellar Templating Approach Introduction Nanocasting - True Liquid Crystalline Templating 3.3 Basics of Micellization Mixed Surfactant Solutions Hierarchical Self-Assembly of Concentrated Aqueous Surfactant Mixtures - Hierarchical Mesoporous Structures Conclusions   COLLOIDAL CRYSTAL TEMPLATING APPROACHES TO MATERIALS WITH HIERARCHICAL POROSITY Introduction and Historical Overview The Preparation of 3DOM Materials 3DOM Materials with Intrinsic Secondary Porosity Hierarchical Materials from Multimodal Colloidal Crystal Templates Hierarchical Materials from Combinations of Soft and Colloidal Crystal Templating Hierarchical Opals and Related Structures Conclusions and Outlook   TEMPLATING OF MACROPOROUS OR SWOLLEN MACROSTRUCTURED POLYMERS Introduction Macroporous Polymer Gels Formed in Amphiphile Solutions Macroporous Starch or Agarose Gels Polymer Foams Polymeric Films and Fibrous Mats Polymer Spheres Closing Remarks   BIOINSPIRED APPROACH TO SYNTHESIZING HIERARCHICAL POROUS MATERIALS Introduction Hierarchical Porous Materials from Biotemplates Hierarchical Porous Materials from the Biomimetic Process Conclusions and Perspectives   POROUS MATERIALS BY TEMPLATING OF SMALL LIQUID DROPS Introduction Emulsion Templating Breath Figures Templating Conclusions   HIERARCHICALLY POROUS MATERIALS BY PHASE SEPARATION: MONOLITHS Introduction Background and Concepts Examples of Materials with Controlled Macro/Mesopores Summary   FEATURE SYNTHESIS OF HIERARCHICALLY POROUS MATERIALS BASED ON GREEN EASY-LEACHING CONCEPT Introduction Hierarchically Structured Porous Materials Synthesized by Easy-Leaching Air Templates Hierarchically Structured Porous Materials Synthesized by Easy-Leaching Ice Template Hierarchically Structured Porous Materials Synthesized by Easy Selective-Leaching Method Other Easy-Leaching Concepts in the Synthesis of Hierarchically Structured Porous Materials Summary   INTEGRATIVE CHEMISTRY ROUTES TOWARD ADVANCED FUNCTIONAL HIERARCHICAL FOAMS Introduction Organic-Inorganic PolyHIPEs Prepared from Water-in-Oil Emulsions Organic-Inorganic PolyHIPEs Prepared from Direct Emulsions Particles-Stabilized PolyHIPE Conclusion and Perspectives   HIERARCHICALLY STRUCTURED POROUS COATINGS AND MEMBRANES Introduction The Multiple Templating Strategy Dynamic Templating Building Block Assemblies for Photonic Band Gap Materials Ink-Jet Printing and Cooperative Self-Assembly Foaming Processes Filtration Membranes Conclusion   SELF-FORMATION PHENOMENON TO HIERARCHICALLY STRUCTURED POROUS MATERIALS Introduction History of Self-Formation Phenomenon Features of Self-Formation Phenomenon Structural Features of Hierarchical Porous Materials Based on the Self-Formation Phenomenon The Mechanism of Self-Formation Procedure Controlled Synthesis Based on the Self-Formation Phenomena Development of Synthesis Methodology Applications and Hierarchical Catalysis Summary   AUTO-GENERATED HIERARCHICAL MESO-MACROPOROUS ALUMINOSILICATE MATERIALS WITH HIGH TETRAHEDRAL AL CONTENT FROM THE SINGLE-MOLECULAR ALKOXY-PRECURSOR (SMAP) STRATEGY Introduction Hierarchically Structured Meso-Macroporous Aluminosilicates Conclusion   ZEOLITES WITH HIERARCHICALLY POROUS STRU

Über Autor(innen)

Bao-Lian Su is Director of the Research Centre for Nanomaterials Chemistry and of the Laboratory of Inorganic Materials Chemistry at the University of Namur; Vice-Director of State Key Laboratory of Advanced Technology for Materials Synthesis and Processing at the Wuhan University of Technology.   Clément Sanchez obtained his PhD degree from Paris University in 1981 and currently holds a post as Professor of Chemistry of Hybrid Materials at the Collège de France. He is also the Director of the Laboratoire de Chimie de la Matière Condensée de Paris at the University P. M. Curie.   Xiao-Yu Yang is a Research Fellow of the FNRS (National Foundation of Scientific Research) at the University of Namur (FUNDP) and Secretary-General of International Materials Forum (IMF) and assistant Director of the Laboratory of Living Materials at the Wuhan University of technology.