Wohlfarth CRC Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutions

1. Auflage 2010
ISBN: 978-1-4398-5039-8
Verlag: Taylor & Francis
Format: PDF
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 551 Seiten

Ten years after the debut of the expansive CRC Handbook of Thermodynamic Data of Copolymer Solutions, The CRC Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutions updates and expands the world’s first comprehensive source of this vital data. Author Christian Wohlfarth, a chemical thermodynamicist specializing in phase equilibria of polymer and copolymer solutions and a respected contributor to the CRC Handbook of Chemistry and Physics, has gathered up-to-the-minute data from more than 500 newly published references. Fully committed to ensuring the reliability of the data, the author included only results with published or personally communicated numerical values.

With volumetric, calormetric, and various phase equilibrium data on more than 450 copolymers and 130 solvents, this handbook furnishes:

- 150 new vapor-liquid equilibrium datasets

- 50 new tables containing classical Henry’s coefficients

- 250 new liquid-liquid equilibrium datasets

- 350 new high-pressure fluid phase equilibrium

- 70 new PVT-properties datasets

- 40 new enthalpic datasets

- Expanded second osmotic virial coefficients data table

Carefully organized, clearly presented, and fully referenced, The Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutions will prove a cardinal contribution to the open literature and invaluable to anyone working with copolymers.

Zielgruppe

Polymer chemists, chemical engineers, and physical chemists.

Autoren/Hrsg.

Wohlfarth, Christian

Fachgebiete

• Naturwissenschaften Chemie Organische Chemie Polymerchemie
• Technische Wissenschaften Verfahrenstechnik | Chemieingenieurwesen | Biotechnologie Technologie der Kunststoffe und Polymere
• Naturwissenschaften Chemie Physikalische Chemie

Inhaltsverzeichnis

INTRODUCTION
Objectives of the handbook
Experimental methods involved
Guide to the data tables
List of symbols
References
VAPOR-LIQUID EQUILIBRIUM (VLE) AND GAS SOLUBILTIES OF COPOLYMER SOLUTIONS
Binary copolymer solutions
Table of binary systems where data were published only in graphical form as phase diagrams or related figures
Ternary and quaternary copolymer solutions
Table of ternary or quaternary systems where data were published only in graphical form as phase diagrams or related figures
Classical mass-fraction Henry's constants of solvent vapors in molten copolymers
References
LIQUID-LIQUID EQUILIBRIUM (LLE) DATA OF COPOLYMER SOLUTIONS
Cloud-point and/or coexistence curves of quasibinary solutions
Table of binary systems where data were published only in graphical form as phase diagrams or related figures
Cloud-point and/or coexistence curves of quasiternary and/or quasiquaternary solutions
Table of ternary or quaternary systems where data were published only in graphical form as phase diagrams or related figures
Upper critical (UCST) and/or lower critical (LCST) solution temperatures
References
HIGH-PRESSURE FLUID PHASE EQUILIBRIUM (HPPE) DATA OF COPOLYMER SOLUTIONS
Cloud-point and/or coexistence curves of quasibinary solutions
Table of binary systems where data were published only in graphical form as phase diagrams or related figures
Cloud-point and/or coexistence curves of quasiternary and/or quasiquaternary solutions
Table of ternary or quaternary systems where data were published only in graphical form as phase diagrams or related figures
References
ENTHALPY CHANGES FOR COPOLYMER SOLUTIONS
Enthalpies of mixing or intermediary enthalpies of dilution, copolymer partial enthalpies of mixing (at infinite dilution), or copolymer (first) integral enthalpies of solution
Partial molar enthalpies of mixing at infinite dilution and enthalpies of solution of gases/vapors of solvents in molten copolymers from inverse gas-liquid chromatography (IGC)
Table of systems where additional information on enthalpy effects in copolymer solutions can be found
References
PVT DATA OF COPOLYMERS AND SOLUTIONS
PVT data of copolymers
Excess volumes and/or densities of copolymer solutions
References
SECOND VIRIAL COEFFICIENTS (A2) OF COPOLYMER SOLUTIONS
Experimental A2 data
References
APPENDICES
Appendix 1 List of copolymers in alphabetical order
Appendix 2 List of systems and properties in order of the copolymers
Appendix 3 List of solvents in alphabetical order
Appendix 4 List of solvents in order of their molecular formulas
INDEX

Über Autor(innen)

Christian Wohlfarth is Associate Professor for Physical Chemistry at Martin Luther University in Halle-Wittenberg, Germany.