Buch, Englisch, Band 214, 186 Seiten, HC runder Rücken kaschiert, Format (B × H): 160 mm x 241 mm, Gewicht: 1030 g
Reihe: Topics in Current Chemistry
Excited States, Transitions, Interactions II
Buch, Englisch, Band 214, 186 Seiten, HC runder Rücken kaschiert, Format (B × H): 160 mm x 241 mm, Gewicht: 1030 g
Reihe: Topics in Current Chemistry
ISBN: 978-3-540-67976-9
Verlag: Springer Berlin Heidelberg
There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements.
Zielgruppe
Research
Fachgebiete
- Naturwissenschaften Chemie Chemie Allgemein
- Naturwissenschaften Chemie Anorganische Chemie Nichtmetallische Chemie
- Naturwissenschaften Chemie Organische Chemie Organometallchemie
- Naturwissenschaften Chemie Organische Chemie Supramolekularchemie
- Naturwissenschaften Chemie Physikalische Chemie Thermochemie, Chemische Thermodynamik
- Naturwissenschaften Chemie Analytische Chemie Massenspektrometrie, Spektroskopie, Spektrochemie
- Naturwissenschaften Chemie Anorganische Chemie Komplexchemie
- Naturwissenschaften Chemie Anorganische Chemie Festkörperchemie
Weitere Infos & Material
Upconversion Processes in Transition Metal and Rare Earth Metal Systems.- Geometric and Electronic Information from the Spectroscopy of Six-Coordinate Copper(II) Compounds.- Low-Lying Electronic States and Photophysical Properties of Organometallic Pd(II) and Pt(II) Compounds. Modern Research Trends Presented in Detailed Case Studies.
