Fundamentals of Ceramics

1. Auflage 2002
ISBN: 978-0-7503-0902-8
Verlag: CRC Press

Buch, Englisch, 624 Seiten, Format (B × H): 164 mm x 234 mm, Gewicht: 1066 g

Reihe: Series in Materials Science and Engineering

Updated and improved, this revised edition of Michel Barsoum's classic text Fundamentals of Ceramics presents readers with an exceptionally clear and comprehensive introduction to ceramic science. Barsoum offers introductory coverage of ceramics, their structures, and properties, with a distinct emphasis on solid state physics and chemistry. Key equations are derived from first principles to ensure a thorough understanding of the concepts involved.The book divides naturally into two parts. Chapters 1 to 9 consider bonding in ceramics and their resultant physical structures, and the electrical, thermal, and other properties that are dependent on bonding type. The second part (Chapters 11 to 16) deals with those factors that are determined by microstructure, such as fracture and fatigue, and thermal, dielectric, magnetic, and optical properties. Linking the two sections is Chapter 10, which describes sintering, grain growth, and the development of microstructure.Fundamentals of Ceramics is ideally suited to senior undergraduate and graduate students of materials science and engineering and related subjects.

Zielgruppe

Senior undergraduate and graduate students in materials science and engineering; chemists and solid state physicists

Autoren/Hrsg.

Barsoum, M. W.

Barsoum, Michel

Fachgebiete

• Naturwissenschaften Physik Thermodynamik Festkörperphysik, Kondensierte Materie
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Werkstoffkunde, Materialwissenschaft: Forschungsmethoden
• Technische Wissenschaften Maschinenbau | Werkstoffkunde Technische Mechanik | Werkstoffkunde Materialwissenschaft: Verbundwerkstoffe

Inhaltsverzeichnis

INTRODUCTIONIntroduction Definition of Ceramics Elementary Crystallography Ceramic Microstructures Traditional Versus Advanced Ceramics General Characteristics of Ceramics ApplicationsThe FutureBONDING IN CERAMICS Introduction Structure of Atoms Ionic versus Covalent Bonding Ionic Bonding Ionically Bonded Solids Covalent Bond Formation Covalently Bonded Solids Band Theory of SolidsSummary Appendix 2A: Kinetic Energy of Free ElectronsSTRUCTURE OF CERAMICS IntroductionCeramic Structures Binary Ionic Compounds Composite Crystal Structures Structure of Covalent Ceramics Structure of SilicatesLattice Parameters and DensitySummary Appendix 3A: Ionic RadiiEFFECT OF CHEMICAL FORCES ON PHYSICAL PROPERTIESIntroduction Melting PointsThermal ExpansionYoung's Modulus and the Strength of Perfect Solids Surface Energy SummaryTHERMODYNAMIC AND KINETIC CONSIDERATIONS Introduction Free EnergyChemical Equilibrium and the Mass Action Expression Chemical Stability Domains Electrochemical Potentials Charged Interfaces, Double Layers, and Debye Lengths Gibbs-Duhem Relation for Binary Oxides Kinetic Considerations Summary Appendix 5A: Derivation of Eq. (5.27)DEFECTS IN CERAMICS IntroductionPoint Defects Linear Defects Planar Defects SummaryDIFFUSION AND ELECTRICAL CONDUCTIVITYIntroductionDiffusion Electrical Conductivity Ambipolar Diffusion Relationships between Self-, Tracer, Chemical, Ambipolar, and Defect Diffusion Coefficients SummaryAppendix 7A: Relationship between Fick's First Law and Eq. (7.30) Appendix 7B: Effective Mass and Density of States Appendix 7C: Derivation of Eq. (7.79) Appendix 7D: Derivation of Eq. (7.92)PHASE EQUILIBRIA IntroductionPhase RuleOne-Component SystemsBinary Systems Ternary Systems Free-Energy Composition and Temperature Diagrams SummaryFORMATION, STRUCTURE, AND PROPERTIES OF GLASSES Introduction Glass Formation Glass Structure Glass Properties Glass-Ceramics Summary Appendix 9A: Derivation of Eq. (9.7)SINTERING AND GRAIN GROWTH IntroductionSolid-State SinteringLiquid-Phase SinteringHot Pressing and Hot Isostatic Pressing Summary Appendix 10A: Derivation of the Gibbs-Thompson Equation Appendix 10B: Radii of Curvature Appendix 10C: Derivation of Eq. (10.20) Appendix 10D: Derivation of Eq. (10.22)MECHANICAL PROPERTIES: FAST FRACTUREIntroduction Fracture Toughness Strength of Ceramics Toughening Mechanisms Designing with Ceramics SummaryCREEP, SUBCRITICAL CRACK GROWTH, AND FATIGUE IntroductionCreepSubcritical Crack Growth Fatigue of CeramicsLifetime Predictions Summary Appendix 12A: Derivation of Eq. (12.24)THERMAL PROPERTIES IntroductionThermal Stresses Thermal Shock Spontaneous Microcracking of Ceramics Thermal Tempering of Glass Thermal Conductivity SummaryDIELECTRIC PROPERTIESIntroduction Basic TheoryEquivalent Circuit Description of Linear Dielectrics Polarization Mechanisms Dielectric Loss Dielectric Breakdown Capacitors and Insulators SummaryAppendix 14A: Local Electric FieldMAGNETIC AND NONLINEAR DIELECTRIC PROPERTIES Introduction Basic Theory Microscopic Theory Para-, Ferro-, Antiferro-, and Ferrimagnetism Magnetic Domains and the Hysteresis Curve Magnetic Ceramics and their Applications Piezo- and Ferroelectric Ceramics SummaryAppendix 15A: Orbital Magnetic Quantum NumberOPTICAL PROPERTIESIntroduction Basic Principles Absorption and Transmission Scattering and Opacity Fiber Optics and Optical Communication Summary Appendix 16A: Coherence Appendix 16B: Assumptions Made in Deriving Eq. (16.24)INDEX*Each chapter contains Problems and Additional Reading.