Herrmann Synthetic Methods of Organometallic and Inorganic Chemistry, Volume 9, 2000
1. Auflage 2014
ISBN: 978-3-13-179251-8
Verlag: Thieme
Format: PDF
Kopierschutz: 1 - PDF Watermark
Volume 9: Transition Metals Part 3
E-Book, Englisch, 233 Seiten, PDF
ISBN: 978-3-13-179251-8
Verlag: Thieme
Format: PDF
Kopierschutz: 1 - PDF Watermark
Zielgruppe
Wissenschaftler
Autoren/Hrsg.
Fachgebiete
Weitere Infos & Material
1;Preface to the Series
Synthetic Methods of Organometallic and Inorganic Chemistry;5
2;Preface to Volume 9;7
3;Contents;8
4;Chapter 1:
Alkenyl, Allyl, and Dienyl Complexes of Main Group Elements and Transition Metals;11
4.1;1.1 Introduction;12
4.2;1.2 1-Alkenyl Compounds;13
4.2.1;1.2.1 General Syntheses of Transition Metal-Vinyl Complexes;14
4.2.2;1.2.2 Main Group Elements;17
4.2.3;1.2.3 Transition Metal Compounds;19
4.3;1.3 Allyl Compounds;23
4.3.1;1.3.1 Main Group Compounds;23
4.3.2;1.3.2 Transition Metal Compounds;29
4.4;1.4 Dienyl Compounds;53
4.5;1.5 Polyenyl Metal Complexes;60
5;Chapter 2: p
-Complexes with HeterocyclicLigands;63
5.1;2.1 Introduction;64
5.2;2.2 Pentamethylpyrrole Complexes;67
5.3;2.3 (. 5-Pyrrolyl)tricarbonylmanganese (Azacymantrene)
;69
5.4;2.4 (.5-Cyclopentadienyl)(.
5-1H-pyrrol-1-y1)fron (Azaferrocene);70
5.5;2.5 2,5-Di-tert.-butyl-l-azacyclopentadienylmetal Complexes;72
5.6;2.6 .
5-Phospholy1 Complexes of Early Transition Metals;74
5.6.1;2.6.1 Synthesis of the Phospholyl Precursors;75
5.6.2;2.6.2 Synthesis of the Phospholyl Complexes;78
5.7;2.7 4,5-Diphenyl-1,3-Diphospholide Anion and (.5-4,5-Dipheny1-1,3-diphospholy1)(.
5-cyclopentadienyl)iron;82
5.8;2.8 2,21 ,5,5'-Tetrakis(trimethylsilyl)-3,3',4,4'-tetramethyl-1,1'-distibaferrocen e
;86
5.9;2.9 Bis(1-tert.-butyl-2-methyl-1H-1,2-azaborolyl)iron and (Wert.-Buty1-2-methy1-1H-1,2-azaborolyl
)(dicarbonyl)cobalt;90
6;Chapter 3:
Complexes of N-Heterocyclic Carbenes;94
6.1;3.1 Introduction;95
6.2;3.2 High-Yielding Synthesis of Functionalized N-Heterocyclic
Carbenes in Liquid Ammonia;95
6.3;3.3 Synthesis of NHC Complexes by a Metalla-Ugi Reaction;97
6.4;3.4 Nickel(II) Complexes;98
6.5;3.5 Nickel(0) Complexes;100
6.6;3.6 Palladium(II) Complexes;102
6.7;3.7 Immobilization of Pd(II)-NHC Complexes;107
6.8;3.8 Palladium(0) Complexes;111
6.9;3.9 Iridium(III) Complexes;114
6.10;3.10 Ruthenium(II) Complexes;116
7;Chapter 4:
Oxo- and Alkoxy-Complexes;123
7.1;4.1 Alkyltrioxometal Compounds;124
7.2;4.2 Oxohalides of Molybdenum and Tungsten;127
7.2.1;4.2.1 Tetrachlorooxomolybdenum and -tungsten;127
7.2.2;4.2.2 Dichlorodioxomolybdenum and -tungsten;128
7.2.3;4.2.3 Dichlorodioxobis(triphenylphosphane oxide)molybdenum and -tungsten,Dioxotungstenacetylacetonate;129
7.3;4.3 Trichlorooxotungsten Compounds with Pyridyl Alcoholate Ligands;131
7.4;4.4 Dioxomolybdenum and -tungsten Compounds with Pyridyl
Alcoholate Ligands;133
7.5;4.5 Other Complexes with Pyridyl Alcoholate Ligands;137
7.5.1;4.5.1 Rhenium(V) Complexes;137
7.5.2;4.5.2 Palladium and Copper Complexes;140
7.6;4.6 Solvent Adducts of (Dibromo)dioxomolybdenum(VI);141
7.7;4.7 Lewis Base Adducts of Dihalodioxomolybdenum(VI);144
7.7.1;4.7.1 Dihalo(1,4-di-p-toly1-1,4-diazabuta-1,3-diene)dioxomolybdenum(VI);144
7.7.2;4.7.2 (1,4-Di-tert.-buty1-1,4-diazabuta- 1,3-diene)dihalodioxomolybdenum(VI);145
7.7.3;4.8 Trigonal Bipyramidal Lewis Base Adducts of Methyltrioxorhenium(VII);147
7.7.3.1;4.8.1 Pyridine Adducts of Methyltrioxorhenium;147
7.7.3.2;4.8.2 Bipyridine Adducts of Methyltrioxorhenium;148
8;Chapter 5: Highly Reduced TantalumCarbonyls Derived from the Hexacarbonyltantalum Anion;151
8.1;5.1 Hexacarbonyltantalates(1—);152
8.2;5.2 Pentacarbonyltantalates(3—);155
8.3;5.3 Pentacarbonylhydridotantalates(2—);157
8.4;5.4 (Ammine)(pentacarbonyl)tantalates(1—);158
8.5;5.5 (tert.-Butyl Isocyanide)(pentacarbonyl)tantalates(1—);159
8.6;5.6 (Cyano)(pentacarbonyl)tantalates(2—);160
9;Chapter 6: Water-Soluble Metal Complexes of Sulfonated Triphenylphosphane
(TPPTS);163
9.1;6.1 Introduction;164
9.2;6.2 General Remarks;165
9.3;6.3 Gel Permeation Chromatography;165
9.3.1;6.3.1 Apparatus;165
9.3.2;6.3.2 Column Packing;167
9.4;6.4 Sulfonated Phosphanes;168
9.5;6.5 TPPTS-Metal Complexes;170
10;Chapter 7:
Miscellaneous Complexes;188
10.1;7.1 (Pentamethylcyclopentadienyl)(phosphane)ruthenium Complexes;189
10.2;7.2 Ally! and Phosphane Complexes of Palladium;192
10.3;7.3 A Selection of Important Alkylidene-Metal Complexes;195
10.3.1;7.3.1 Introduction;195
10.3.2;7.3.2 Ruthenium-Alkylidene Complexes;195
10.3.3;7.3.3 Tungsten-Alkylidene Complexes;197
10.3.4;7.3.4 Ruthenium-Vinylidene- and -Allenylidene Complexes;199
10.4;7.4 Bisimino Systems (Brookhart/Gibson Systems);206
11;Index;213
12;List of Transition Metal Complexes in other Volumes;229