Li / Liu Bridging Heterogeneous and Homogeneous Catalysis

Concepts, Strategies, and Applications
1. erweiterte Auflage 2014
ISBN: 978-3-527-67592-0
Verlag: Wiley-VCH
Format: EPUB
Kopierschutz: Adobe DRM (»Systemvoraussetzungen)

E-Book, Englisch, 656 Seiten, E-Book

There are two main disciplines in catalysis research -- homogeneous and heterogeneous catalysis. This is due to the fact that the catalyst is either in the same phase (homogeneous catalysis) as the reaction being catalyzed or in a different phase (heterogeneous catalysis). Over the past decade, various approaches have been implemented to combine the advantages of homogeneous catalysis (efficiency, selectivity) with those of heterogeneous catalysis (stability, recovery) by the heterogenization of homogeneous catalysts or by carrying out homogeneous reactions under heterogeneous conditions.

This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis.

Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations.

With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.

Autoren/Hrsg.

Li, Can

Liu, Yan

Inhaltsverzeichnis

Preface

 

ACID-BASE COOPERATIVE CATALYSIS FOR ORGANIC REACTIONS BY DESIGNED SOLID SURFACES WITH ORGANOFUNCTIONAL GROUPS

Introduction

Bifunctional Catalysts Possessing both Acidic and Basic Organic Groups

Bifunctional Catalysts Possessing Basid Organic Groups and Acid Sites Derived from their Support Surface

Prospect

 

CATALYTIC REACTIONS IN OR BY ROOM TEMPERATURE IONIC LIQUIDS: BRIDGING THE GAP BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSIS

Introduction and Background

Catalysis with IL-Supported or Mediated Metal Nanoparticles

Reactions Catalyzed by Solids Support IL: Heterogeneous Catalysis with Homogeneous Performance

Outlook

 

HETEROGENEOUS CATALYSIS WITH ORGANI-INORGANIC HYBRID MATERIALS

Introduction

Organic-Inorganic Hybrid Materials

Catalytic Applications of Organic-Inorganic Hybrid Materials

Conclusion

 

HOMOGENEOUS ASYMMETRIC CATALYSIS USING IMMOBILIZED CHIRAL CATALYSTS

Introduction

Soluble Polymeric Supports and Catalyst Separation Methods

Chiral Linear Polymeric Catalysts

Chiral Dendritic Catalysts

Helical Polymeric Catalysts

Conclusion and Prospect

 

ENDEAVORS TO BRIDGE THE GAP BETWEEN HOMO- & HETEROGENEOUS ASYMMETRIC CATALYSIS WITH ORGANOMETALLICS

General Introduction

Combinatorial Approach for Homogeneous Asymmetric Catalysis

Self-Supporting Approach for Heterogeneous Asymmetric Catalysis

Conclusions and Outlook

 

CATALYSIS IN AND ON WATER

Introduction

Catalytic Reactions in and "on" Water

Conclusion

 

A GREEN CHEMISTRY STRATEGY: FLUOROUS CATALYSIS

History of Fluorous Chemistry

Basics of Fluorous Chemistry

Fluorous Metallic Catalysis

Fluorous Organocatalysis

Conclusion

 

EMULSION CATALYSIS: INTERFACE BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSIS

Introduction

Emulsion Catalysis in the Oxidative Desulfurization

Emulsion Catalysis in the Lewis Acid-Catalyzed Organic Reaction

Emulsion Catalysis in Reactions with Organocatalysts

Emulsion Formed with Polymer Bounded Catalysts

Conclusion and Perspective

 

IDENTIFICATION OF BINDING AND REACTIVE SITES IN METAL CLUSTER CATALYSIS: HOMOGENEOUS-HETEROGENEOUS BRIDGES

Introduction

Control of Binding in Metal-Carbonyl Clusters via Ligand Effects

Imaging of CO Binding on Nobel Metal Clusters

Imaging of Open Sites in Metal Cluster Catalysis

Elucidating Kinetic Contributions of Open Sites: Kinetic Poisoning Experiments Using Organic Ligands

More Approaches to Poisoning Open Catalytic Active Sites to Obtain Structure Function Relationships

Supported Molecular Iridium Clusters for Ethylene Hydrogenation

Summary and Outlook

 

CATALYSIS IN POROUS-MATERIAL-BASED NANOREACTORS: A BRIDGE BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSIS

Introduction

Preparation of Nanoreactors Based on Porous Materials

Assembly of the Molecular Catalysts in Nanoreactor

Catalytic Reactions in Nanoreactor

Conclusions and Perspectives

 

HETEROGENEOUS CATALYSIS BY GOLD CLUSTERS

Introduction

Preparation of Gold Clusters

Characterization of Gold Clusters

Catalysis by Gold Clusters

Conclusions and Perspectives

 

ASYMMETRIC PHASE-TRANSFER CATALYSIS IN ORGANIC SYNTHESIS

Introduction

Chiral Phase-Transfer Catalysts

Asymmetric Phase-Transfer Catalytic Reactions and Applications

Concluding Remarks

 

CATALYSIS IN SUPERCRITICAL FLUIDS

Introduction

Features of Supercritical Fluids and Related Catalytic Reactions

Examples of the Reactions in SCFs

Summary and Conclusions

 

HYDROFORMYLATION OF OLEFINS IN AQUEOUS-ORGANIC BIPHASIC CATALYTIC SYSTEMS

Introduction

Water-Soluble Rhodium Phosphin Complex Catalytic Systems

Mechanism

Hydroformylation of Lower Olefins

Hydroformulation of Higher Olefin

Hydroformulation of Internal Olefins

Conclusion and Outlook

 

RECENT PROGRESS IN ENZYME CATALYSIS IN REVERSE MICELLES

Introduction

Enzyme Catalysis in Molecular Organic Solvent-Based Reverse Micelles

Enzyme Catalysis in Ionic Liquid-Based Reverse Micelles

Applications of Enzyme Catalysis in Reverse Micelles

Concluding Remarks

 

THE MOLECULAR KINETICS OF THE FISCHER-TROPSCH REACTION

Introduction

Basics of FT Kinetics

Molecular Microkinetics Simulations

Über Autor(innen)

Can Li received his PhD degree from the Dalian Institute of Chemical Physics (China) in 1988, was promoted to full professor in 1993, and was elected as a member of the Chinese Academy of Sciences in 2003. He was appointed director of the State Key Laboratory of Catalysis at the Dalian Institute of Chemical Physics in 1998 and elected to the President of the International Association of Catalysis Societies in 2008. He is a member of the editorial board of more than 15 academic journals and has published more than 400 peer-reviewed papers, authorized 40 patents and delivered more than 60 invited and plenary lectures at national and international conferences. Under his supervision, more than 60 graduate students have obtained their PhD degrees. Among the prestigious awards he received are the International Catalysis Award, the National Award for Outstanding Young Scientists in China, and the HoLeungHoLee Prize. His research interests are physical chemistry, catalysis, environmental catalysis, chiral catalysis, in-situ characterization, resonance and time-resolved spectroscopy, and solar energy utilization (photocatalysis, photoelectrocatalysis and photovoltaic).

 

Yan Liu studied chemistry at Lanzhou University (China) and then moved to the State Key Laboratory of Organometallic Chemistry at the Shanghai Institute of Organic Chemistry to obtain his PhD degree under the supervision of Prof. Kuiling Ding in 2006. After three years of postdoctoral studies with Prof. Li Deng, Brandeis University (USA), he joined Prof. Can Li?s group at the State Key Laboratory of Catalysis at the Dalian Institute of Chemical Physics in 2010 as associate professor and was promoted to full professor in 2013.