Zimmer Annual Reports in Inorganic and General Syntheses-1976

1. Auflage 2013
ISBN: 978-1-4832-8159-9
Verlag: Elsevier Science & Techn.
Format: PDF
Kopierschutz: 1 - PDF Watermark

E-Book, Englisch, 404 Seiten, Web PDF

Annual Reports in Inorganic and General Syntheses-1976 presents an annual review of synthetically useful information that would prove beneficial to nearly all organic chemists, both specialist and nonspecialist in synthesis. It should help relieve some of the information storage burden of the specialist and should aid the nonspecialist who is seeking help with a specific problem to become rapidly aware of recent synthetic advances. This is the fifth volume of ARIGS and is organized along the lines developed for the preceding volumes. The authors were encouraged to use synthetic aspects as their primary guideline for the arrangement and preservation of the information. An occasional deviation to include structural or mechanistic features seemed to be justified in order to reflect particular characteristics of a given element's chemistry. Complex hydrides of the groups IA-IIIA are dealt with in a special chapter rather than described under the particular elements. As in previous issues of ARIGS, this volume again presents contributions of timely subjects of special interest. This year's special features are 'Recent Advances in S-N-Inorganic Heterocycles' and 'Synthesis and Properties of Optically Active Organotin Compounds.'

Autoren/Hrsg.

Zimmer, Hans

Inhaltsverzeichnis

1;Front Cover
;1
2;Annual Reports in Inorganic and General Syntheses–1976;4
3;Copyright Page;5
4;Table of Contents
;6
5;PREFACE;10
6;CHAPTER 1. SIMPLE AND COMPLEX METAL HYDRIDES OF MAIN GROUPS I, II AND III;12
6.1;ALKALI METAL HYDRIDES;12
6.2;BERYLLIUM HYDRIDE;13
6.3;HALOBERYLLIUM HYDRIDE COMPLEXES;14
6.4;TERTIARY AMINE COMPLEXES OF BeH2;14
6.5;ALKYLBERYLLIUM HYDRIDES;14
6.6;MAGNESIUM HYDRIDE;14
6.7;ALUMINUM HYDRIDE;14
6.8;ALUMINUM HALOHYDRIDE AMINE COMPLEXES;16
6.9;HYDRIDOALUMINATES;17
6.10;SODIUM TETRAHYDRIDOALUMINATE;17
6.11;SODIUM HEXAHYDRIDOALUMINATE;17
6.12;COMPOUNDS BETWEEN TETRAHYDRIDOALUMINATES AND AIH3;18
6.13;ALKALI METAL HYDRIDOALUMINATES OF Na, K, Rb AND Cs;18
6.14;REFERENCES;19
7; CHAPTER 2. BORON;22
7.1;GENERAL;22
7.2;REACTION METHODS;23
7.3;METAL BORON COMPOUNDS;23
7.4;ORGANOBORANES;24
7.5;BORANES AND CARBORANES;25
7.6;RING SYSTEMS;26
7.7;FOUR COORDINATE BORON;26
7.8;REFERENCES;27
8;CHAPTER 3. ALUMINUM, GALLIUM, INDIUM AND THALLIUM;30
8.1;Reviews;30
8.2;Reactions of Metal Halides;30
8.3;Special Techniques;32
8.4;Exchange Reactions;32
8.5;Metal Carbonyls;33
8.6;Nitrate and Chlorate Complexes;33
8.7;Perhalo Complexes;33
8.8;Novel Syntheses;34
8.9;Molecular Elimination Reactions;34
8.10;Insertion Reactions;35
8.11;Reactions of Metal Alkyls;35
8.12;Hydrides;36
8.13;Catalysis;36
8.14;Miscellaneous Complexes with O, S, N and P Donor Ligands;37
8.15;Group III - Group IV Bonds;39
8.16;REFERENCES;40
9;CHAPTER 4. SILICON CHEMISTRY;43
9.1;GENERAL;43
9.2;SILICON-HYDROGEN;43
9.3;SILICON-GBOUP IV;44
9.4;SILICON-GROUP V;48
9.5;SILICON-GROUP VI;50
9.6;SILICON-GROUP VII;51
9.7;SILICON-METAL BONDS;52
9.8;REFERENCES;53
10;CHAPTER 5. Germanium, Tin and Lead;60
10.1;Metal-Carbon Bonded Compounds;60
10.2;Metallocycles and Metalsubstituted Ring Systems;61
10.3;Metal-Halogen Compounds;62
10.4;Metal-Oxygen or Sulfur Compounds;63
10.5;Metal-Nitrogen Compounds;65
10.6;Metal-Phosphorus Compounds;65
10.7;Metal-Metal Compounds;66
10.8;Metal-Transition Metal Compounds;66
11;CHAPTER 6. NITROGEN;75
11.1;GENERAL;75
11.2;COMPOUNDS WITH NO N-N BONDS;75
11.3;COMPOUNDS WITH ONE OR MORE N-N BONDS;79
11.4;REFERENCES;80
12;CHAPTER 7. PHOSPHORUS PHOSPHIDES AND PHOSPHORUS COMPOUNDS WITH THE COORDINATION NUMBERS 2, 3, 5, AND 6;83
12.1;INTRODUCTION;83
12.2;PHOSPHIDES;83
12.3;PHOSPHORUS COMPOUNDS WITH COORDINATION NUMBER 2;83
12.4;PHOSPHORUS COMPOUNDS WITH COORDINATION NUMBER 3 SIMPLE PHOSPHANES (PXYZ);85
12.5;COMPOUNDS WITH P - P BONDS;94
12.6;DERIVATIVES OF PHOSPHORUS ACID;95
12.7;COMPLEXES;95
12.8;PHOSPHORUS COMPOUNDS WITH COORDINATION NUMBER 5 TRIGONAL-BIPYRAMIDAL PHOSPHORANES;95
12.9;CYCLIC PHOSPHORANES;95
12.10;PHOSPHORUS COMPOUNDS WITH COORDINATION NUMBER 6;96
12.11;REFERENCES;97
13;CHAPTER 8. PHOSPHORUS PHOSPHORUS COMPOUNDS WITH THE COORDINATION NUMBER 4;101
13.1;INTRODUCTION;101
13.2;PHOSPHANESULFIDES, -SELENIDES, AND -TELLURIDES;101
13.3;P-B, P-C, AND P-Si COMPOUNDS;101
13.4;PHOSPHORUS COMPOUNDS WITH ELEMSNTS OF GROUP VA PHOSPHAZANES;102
13.5;PHOSPHAZENES;103
13.6;COMPOUNDS WITH P-P AND P-As BONDS;105
13.7;DERIVATIVES OF PHOSPHOROUS ACID AND PHOSPHONIC ACIDS;106
13.8;DERIVATIVES OP ORTHOPHOSPHORIC ACID;108
13.9;DIPHOSPHATES AND POLYPHOSPHATES;110
13.10;COMPLEXES WITH PHOSPHOR CONTAINING LIGANDS;111
14;CHAPTER 9. ARSENIC, ANTIMONY AND BISMUTH;122
14.1;GENERAL;122
14.2;ARSENIC (III);122
14.3;ANTIMONY (III);125
14.4;BISMUTH III;126
14.5;REFERENCES;126
15;CHAPTER 10. CHALCOGENS;130
15.1;OXYGEN;130
15.2;SULFUR;130
15.3;SELENIUM;131
15.4;TELLURIUM;132
15.5;REFERENCES;133
16;CHAPTER 11. HALOGENS AND PSEUDOHALOGENS;135
16.1;HALOGENS;135
16.2;PSEUDOHALO COMPLEXES OF TRANSITION METALS;139
16.3;REFERENCES;145
17;CHAPTER 12. SCANDIUM, YTTRIUM, LANTHANIDES AND ACTINIDES;149
17.1;GENERAL;149
17.2;SCANDIUM;149
17.3;YTTRIUM AND LANTHANIDES;149
17.4;ACTINIDES;153
17.5;REFERENCES;157
18;CHAPTER 13. TITANIUM, ZIRCONIUM AND HAFNIUM;162
18.1;GENERAL;162
18.2;GROUP O COMPOUNDS;163
18.3;HALIDES AND PSEUDOHALIDES;163
18.4;GROUP VI COMPOUNDS;164
18.5;GROUP V COMPOUNDS;169
18.6;GROUP IV COMPOUNDS;172
18.7;GROUP III COMPOUNDS;172
18.8;HYDRIDES;173
18.9;REFERENCES;174
19;CHAPTER 14. VANADIUM, NIOBIUM, AND TANTALUM;178
19.1;GENERAL;178
19.2;VANADIUM;178
19.3;NIOBIUM AND TANTALUM;182
19.4;REFERENCES;184
20;CHAPTER 15. CHROMIUM, MOLYBDENUM, AND TUNGSTEN;190
20.1;CHROMIUM;190
20.2;MOLYBDENUM;193
20.3;TUNGSTEN;196
20.4;REFERENCES;200
21;CHAPTER 16. MANGANESE, TECHNETIUM AND RHENIUM;210
21.1;GENERAL (1,2);210
21.2;MANGANESE;210
21.3;TECHNETIUM;212
21.4;RHENIUM;213
21.5;REFERENCES;216
22;CHAPTER 17. IRON;224
22.1;GENERAL;224
22.2;COMPOUNDS WITH NITROGEN DONORS;224
22.3;COMPOUNDS WITH CHALCOGEN DONORS;227
22.4;COMPOUNDS WITH HALOGEN LIGANDS;229
22.5;CYANO COMPLEXES;230
22.6;DIMERS AND POLYMERS;231
22.7;REFERENCES;231
23;CHAPTER 18. COBALT and NICKEL;236
23.1;REVIEWS;236
23.2;LOWER OXIDATION STATES - COBALT;236
23.3;COBALT(II) and NICKEL(II) COMPLEXES;241
23.4;HIGHER OXIDATION STATES;246
23.5;REFERENCES;247
24;CHAPTER 19. THE PLATINUM METALS. PART I. RUTHENIUM, OSMIUM, RHODIUM AND IRIDIUM;252
24.1;INTRODUCTION;252
24.2;INTERMETALLIC COMPOUNDS AND RELATED TYPES;252
24.3;GROUP VII DONORS;252
24.4;GROUP VI DONORS;253
24.5;GROUP V DONORS;256
24.6;GROUP IV DONORS;260
24.7;GROUP III DONORS;265
24.8;HYDROGEN DONORS (HYDRIDO COMPLEXES);265
24.9;HETEROBDîETALLIC (METAL-METAL BONDED) COMPLEXES;266
24.10;REFERENCES;266
25;CHAPTER 20. The Platinum Metals PART II: Platinum and Palladium;275
25.1;GROUP VII DONORS;275
25.2;GROUP VI DONORS;275
25.3;GROUP V DONORS;279
25.4;GROUP IV LIGANDS;287
25.5;REFERENCES;295
26;CHAPTER 21. COPPER;304
26.1;GENERAL;304
26.2;COPPER(I) COMPOUNDS;305
26.3;COPPER(II) COMPOUNDS;307
26.4;DIMERS AND POLYMERS;314
26.5;REFERENCES;317
27;CHAPTER 22. SILVER AND GOLD;325
27.1;INTRODUCTION;325
27.2;COMPOUNDS CONTAINING (Ag,Au)-C BONDS;325
27.3;PHOSPHINE COMPLEXES;327
27.4;SIMPLE SALTS AND OTHER COMPLEXES;328
27.5;COMPOUNDS CONTAINING N, O, OR S LIGANDS;328
27.6;MISCELLANEOUS COMPOUNDS;330
27.7;REFERENCES;331
28;CHAPTER 23. ZINC, CADMIUM AND MERCURY;335
28.1;GENERAL AND INORGANIC COMPOUNDS;335
28.2;COORDINATION COMPOUNDS;336
28.3;ORGANOMETALLIC COMPOUNDS;339
28.4;COMPOUNDS WITH METAL-METAL BONDS;343
28.5;REFERENCES;344
29;CHAPTER 24. SYNTHESIS AND PROPERTIES OF OPTICALLY ACTIVE ORGANOTIN COMPOUNDS;348
29.1;1. Introduction;349
29.2;2. Syntheses of optically active functionally substituted tetraorganotin compounds;350
29.3;3. Asymmetric syntheses of optically active tetraorganotin compounds;352
29.4;4. Asymmetric syntheses of optically active triorganotin hydrides;354
29.5;5. Stereoselective syntheses of optically active tetraorganotin compounds from optically active triorganotin hydrides;355
29.6;6. Asymmetric syntheses and optical stability of chiral triorganostannyl-metal compounds;356
29.7;Acknowledgements;357
29.8;Literature;358
30;CHAPTER 25. RECENT ADVANCES IN SULFUR-NITROGEN INORGANIC HETEROCYCLES;361
30.1;INTRODUCTION;361
30.2;BONDING AND THEORETICAL STUDIES;361
30.3;UNSUBSTITUTED SULFUR-NITROGEN HETEROCYCLES (BINARY COMPOUNDS);362
30.4;N-SUBSTITUTED SULFUR-NITROGEN HETEROCYCLES;366
30.5;S-SUBSTITUTED SULFUR-NITROGEN HETEROCYCLES;369
30.6;HETEROATOM SULFUR-NITROGEN HETEROCYCLE5;372
30.7;CONCLUDING REMARKS;376
30.8;REFERENCES;377
31;INDEX;384